Bromide–chloride exchange between alkyl halides and metal halide salts under phase transfer conditions

Author(s):  
Y. Sasson ◽  
M. Weiss ◽  
A. Loupy ◽  
G. Bram ◽  
C. Pardo
Synthesis ◽  
2021 ◽  
Author(s):  
Jean-François Paquin ◽  
Xavier Bertrand ◽  
Pascal Paquin ◽  
Laurent Chabaud

AbstractThe hydrochlorination, hydrobromination, and hydroiodination of unactivated alkenes using methanesulfonic acid and inorganic halide salts (CaCl2, LiBr, LiI) in acetic acid are reported. This approach uses readily available and inexpensive reagents to provide the alkyl halides in up to 99% yield. An example of deuteriochlorination using deuterated acetic acid as the solvent is also demonstrated.


2016 ◽  
Vol 8 (35) ◽  
pp. 23086-23094 ◽  
Author(s):  
Lili Wang ◽  
Dhanashree Moghe ◽  
Soroush Hafezian ◽  
Pei Chen ◽  
Margaret Young ◽  
...  

1988 ◽  
Vol 18 (13) ◽  
pp. 1531-1536 ◽  
Author(s):  
Albert W. M. Lee ◽  
W. H. Chan ◽  
H. C. Wong

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