Optimization of Electrical Performance of Defected n+-p-p+ Solar Cell with CdS/BaSi2/Cu2O Heterostructure Using SCAPs 1D

Present study investigates the performance of BaSi2 based BSF structure solar cell. SCAPS 1D simulator has been employed to investigate the heterostructure solar cell. To decrease the recombination loss due to minority carrier, a new configuration is proposed by inclusion of the p-type cuprous oxide (Cu2O) as BSF layer. The Cu2O BSF layer width varying in range 0.1 to 0.4 µm to analyze the feasibility of device for optimum performance. The anticipated structure consists of ZnO/CdS/BaSi2/Cu2O layers and offers the maximum efficiency of above 24%. Parameters for example open circuit voltage (Voc), short-circuit current density (Jsc), fill factor (FF), conversion efficiency (η) and quantum efficiency (QE) of the device have been analyzed graphically. The optimized structure may have significant impact on future development of advanced photovoltaic devices.

Junction Configuration Effects on the Photovoltaic Parameters of a-Si/CZTS Solar Cells

Due to increased energy intensive human activities resulting accelerated demand for electric power coupled with occurrence of natural disasters with increased frequency, intensity, and duration, it becomes essential to explore and advance renewable energy technology for sustainability of the society. Addressing the stated problem and providing a radical solution has been attempted in this study. To harvest the renewable energy, among variety of solar cells reported, a composite a-Si/CZTS photovoltaic devices has not yet been investigated. The calculated parameters for solar cell based on the new array of layers consisting of a-Si/CZTS are reported in this study. The variation of i) solar cell efficiency as a function of CZTS layer thickness, temperature, acceptor, and donor defect concentration; ii) variation of the open circuit current density as a function of temperature, open circuit voltage; iii) variation of open circuit voltage as a function of the thickness of the CZTS layer has been determined. There has been no reported study on a-Si/CZTS configuration-based solar cell, analysis of the parameters, and study to address the challenges imped efficiency of the photovoltaic device and the same has been discussed in this work. The value of the SnO2/a-Si/CZTS solar cells obtained from the simulation is 23.9 %.

Polarization-insensitive broadband omni-directional anti-reflection in ZnO nanoneedle array for efficient solar energy harvesting

Broadband omni-directional anti-reflection characteristics have been an important issue because they can maximize the optical absorption in photovoltaic devices. Here, we investigate the optical properties of ZnO nanoneedle arrays to...

Полупроводниковые свойства полимерных пленок на основе комплекса никеля с лигандом саленового типа

Complexes of metals with Schiff bases are considered as promising materials for creating energy storage and photovoltaic devices. In this work, the semiconducting properties of a polymer nickel film with a salen-type ligand (poly-Ni(CH3O-Salen)) were studied by spectrophotometric and Faraday impedance spectroscopy. The Mott-Schottky analysis showed that the polymer film is a semiconducting material with a fairly narrow band gap, high charge carrier density and p-type conductivity. Using the method of Faraday impedance spectroscopy, the limiting stage of the oxygen photoelectroreduction reaction, the process of charge transfer from the film to molecular oxygen, has been established.

Impact of substituents on the performance of small-molecule semiconductors in organic photovoltaic devices via regulating morphology

This review summarizes recent prominent examples of substituent engineering on small-molecule organic semiconductors for photovoltaic applications, focusing on flexible substituents that regulate the active-layer morphology.

Ultrafast Triplet Generation at the Lead Halide Perovskite/Rubrene Interface

Triplet sensitization of rubrene by bulk lead halide perovskites has recently resulted in efficient infrared-to-visible photon upconversion via triplet-triplet annihilation. Notably, this process occurrs under solar relavant fluxes, potentially paving the way toward integration with photovoltaic devices. In order to further improve the upconversion efficiency, the fundamental photophysical pathways at the perovskite/rubrene interface must be clearly understood to maximize charge extraction. Here, we utilize ultrafast transient absorption spectroscopy to elucidate the processes underlying the triplet generation at the perovskite/rubrene interface. Based on the bleach and photoinduced absorption features of the perovskite and perovskite/rubrene devices obtained at multiple pump wavelengths and fluences, along with their resultant kinetics, our results do not support charge transfer states or long-lived trap states as the underlying mechanism. Instead, the data points towards a triplet sensitization mechanism based on rapid extraction of thermally excited carriers on the picosecond timescale.