The crystal and molecular structure of 6-bromo-2-(furan-2-yl)-3-(prop-2-ynyl)-3H-imidazo[4,5-b]pyridine (C13H8BrN3O) has been investigated from single crystal X-ray diffraction data. The primary focus is to investigate the molecular geometry of this compound in the solid state along with the associated intermolecular hydrogen bonding and relatedπ-πinteractions present in the crystal packing. This compound crystallizes in the monoclinic space groupP21/nwith cell parameters:a= 4.39655(19) Å,b= 13.5720(5) Å,c= 20.0471(5) Å,β= 94.753(3),V= 1192.10(7) Å3,D= 1.683 g·cm−3, andZ= 4. The crystal structure is stabilized byπ-πinteractions and intermolecular C–H⋯N and C–H⋯O interactions.