scholarly journals Investigation of Pd nanoparticles supported on zeolites for hydrogen production from formic acid dehydrogenation

2015 ◽  
Vol 5 (1) ◽  
pp. 364-371 ◽  
Author(s):  
M. Navlani-García ◽  
M. Martis ◽  
D. Lozano-Castelló ◽  
D. Cazorla-Amorós ◽  
K. Mori ◽  
...  

Palladium nanoparticles supported on different BETA zeolites are promising catalysts for H2production from formic acid dehydrogenation.

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3258
Author(s):  
Hamed M. Alshammari ◽  
Mohammad Hayal Alotaibi ◽  
Obaid F. Aldosari ◽  
Abdulellah S. Alsolami ◽  
Nuha A. Alotaibi ◽  
...  

The present study investigates a process for the selective production of hydrogen from the catalytic decomposition of formic acid in the presence of iridium and iridium–palladium nanoparticles under various conditions. It was found that a loading of 1 wt.% of 2% palladium in the presence of 1% iridium over activated charcoal led to a 43% conversion of formic acid to hydrogen at room temperature after 4 h. Increasing the temperature to 60 °C led to further decomposition and an improvement in conversion yield to 63%. Dilution of formic acid from 0.5 to 0.2 M improved the decomposition, reaching conversion to 81%. The reported process could potentially be used in commercial applications.


2016 ◽  
Vol 1 (9) ◽  
pp. 1879-1886 ◽  
Author(s):  
Miriam Navlani-García ◽  
Kohsuke Mori ◽  
Ai Nozaki ◽  
Yasutaka Kuwahara ◽  
Hiromi Yamashita

2017 ◽  
Vol 5 (31) ◽  
pp. 16150-16161 ◽  
Author(s):  
Katherine Koh ◽  
Mina Jeon ◽  
Chang Won Yoon ◽  
Tewodros Asefa

A series of Pd/SBA-15-amine materials (where “Amine” is primary amine, secondary amine and tertiary amine) containing Pd nanoparticles are synthesized and their catalytic properties for formic acid dehydrogenation are investigated.


ChemSusChem ◽  
2018 ◽  
Vol 11 (19) ◽  
pp. 3396-3401 ◽  
Author(s):  
Yan Leng ◽  
Chenjun Zhang ◽  
Bing Liu ◽  
Miaomiao Liu ◽  
Pingping Jiang ◽  
...  

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