Recent applications of chiral N-tert-butanesulfinyl imines, chiral diene ligands and chiral sulfur–olefin ligands in asymmetric synthesis

2015 ◽  
Vol 2 (1) ◽  
pp. 73-89 ◽  
Author(s):  
Han-Qing Dong ◽  
Ming-Hua Xu ◽  
Chen-Guo Feng ◽  
Xing-Wen Sun ◽  
Guo-Qiang Lin
Keyword(s):  
Asymmetric Synthesis ◽  
Asymmetric Reactions ◽  
Highly Efficient ◽  
Diene Ligands

The highly efficient asymmetric reactions of chiral sulfinyl auxiliary, diene ligands and sulfur–olefin ligands are presented.

Strategies of In Situ Generated Magnesium Catalysis in Asymmetric Reactions

Synlett ◽  
2021 ◽  
Author(s):  
Dongxu Yang ◽  
Linqing Wang
Keyword(s):  
Asymmetric Synthesis ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Asymmetric Reactions ◽  
Chiral Ligands ◽  
Alkaline Earth Metal ◽  
Enantioselective Reactions ◽  
Earth's Crust

AbstractMagnesium (Mg) is a cheap, non-toxic, and recyclable alkaline earth metal that constitutes about 2% weight in the Earth’s crust. The use of magnesium catalysts to forge chiral moieties in molecules is highly attractive. Based on our work in recent years, we describe the current progress in the development of in situ generated magnesium catalysts and their application in asymmetric synthesis. In this perspective, a critically concise classification of in situ generated magnesium catalytic modes, with relevant examples, is presented, and representative mechanisms of each category are discussed. Building on the established diverse strategies, one can foresee that more innovative and structurally creative magnesium catalysts that are generated in situ will be developed to overcome more formidable challenges of catalytic enantioselective reactions.1 Introduction2 Magnesium Catalysts Generated in Situ from Chiral Ligands Containing Dual Reactive Hydrogens3 Magnesium Catalysts Generated in Situ from Monoanionic Chiral Ligands4 Bimetallic and Polymetallic Magnesium Catalysts Assembled in Situ5 Summary and Outlook

HIGHLY EFFICIENT ASYMMETRIC SYNTHESIS OF (S)-2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL FROM GLYCEROL

1984 ◽  
Vol 13 (3) ◽  
pp. 401-404 ◽  
Author(s):  
Teruaki Mukaiyama ◽  
Yoo Tanabe ◽  
Makoto Shimizu
Keyword(s):  
Asymmetric Synthesis ◽  
Highly Efficient

scholarly journals Correction to “Highly Efficient Asymmetric Synthesis of Sitagliptin”

2020 ◽  
Vol 142 (31) ◽  
pp. 13622-13622
Author(s):  
Karl B. Hansen ◽  
Yi Hsiao ◽  
Feng Xu ◽  
Nelo Rivera ◽  
Andrew Clausen ◽  
...  
Keyword(s):  
Asymmetric Synthesis ◽  
Highly Efficient

scholarly journals Asymmetric reactions in continuous flow

2009 ◽  
Vol 5 ◽  
Author(s):  
Xiao Yin Mak ◽  
Paola Laurino ◽  
Peter H Seeberger
Keyword(s):  
Asymmetric Synthesis ◽  
Asymmetric Catalysis ◽  
Continuous Flow ◽  
Asymmetric Reactions ◽  
Heterogeneous Asymmetric Catalysis

An overview of asymmetric synthesis in continuous flow and microreactors is presented in this review. Applications of homogeneous and heterogeneous asymmetric catalysis as well as biocatalysis in flow are discussed.

The First Highly Efficient Asymmetric Synthesis of α-Substituted Methyl Sulfonates

2002 ◽  
Vol 41 (1) ◽  
pp. 109-111 ◽  
Author(s):  
Dieter Enders ◽  
Nicola Vignola ◽  
Otto M. Berner ◽  
Jan W. Bats
Keyword(s):  
Asymmetric Synthesis ◽  
Highly Efficient

Convergent Asymmetric Synthesis of a Renin Inhibitor: A Highly Efficient Construction Method of Three Stereogenic Centers

2013 ◽  
Vol 17 (11) ◽  
pp. 1430-1439 ◽  
Author(s):  
Makoto Michida ◽  
Yoshihiro Takayanagi ◽  
Makoto Imai ◽  
Yukito Furuya ◽  
Kenichi Kimura ◽  
...  
Keyword(s):  
Asymmetric Synthesis ◽  
Construction Method ◽  
Renin Inhibitor ◽  
Highly Efficient ◽  
Stereogenic Centers ◽  
Efficient Construction
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