Highly efficient photocatalytic hydrogen generation by incorporating CdS into ZnCr-layered double hydroxide interlayer

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5823-5829 ◽  
Author(s):  
Guohua Zhang ◽  
Bizhou Lin ◽  
Weiwei Yang ◽  
Shaofeng Jiang ◽  
Qianru Yao ◽  
...  

Incorporating CdS nanoparticles into the interlayer of ZnCr–LDH nanosheets led to the formation of CdS-pillared ZnCr–LDH nanohybrid, which exhibited superior photocatalytic hydrogen-generation performance from water splitting.

2018 ◽  
Vol 6 (25) ◽  
pp. 11670-11675 ◽  
Author(s):  
Hao Chen ◽  
Xiao-Yuan Liu ◽  
Shizhuo Wang ◽  
Xu Wang ◽  
Qi Wei ◽  
...  

Hydrogen generation based on photocatalytic water splitting is a promising strategy for renewable energy production.


2018 ◽  
Vol 6 (7) ◽  
pp. 3224-3230 ◽  
Author(s):  
Li-Ming Cao ◽  
Jia-Wei Wang ◽  
Di-Chang Zhong ◽  
Tong-Bu Lu

The development of readily available, highly efficient and stable electrocatalysts for the oxygen evolution reaction (OER) is extremely significant to facilitate water splitting for the generation of clean hydrogen energy.


2019 ◽  
Vol 7 (6) ◽  
pp. 2831-2837 ◽  
Author(s):  
Qing Yan ◽  
Peng Yan ◽  
Tong Wei ◽  
Guiling Wang ◽  
Kui Cheng ◽  
...  

A highly-efficient water splitting device is assembled with the platinum sub-nanoclusters functionalized nickel iron layered double hydroxides and hierarchical nickel iron selenides.


NANO ◽  
2019 ◽  
Vol 14 (11) ◽  
pp. 1950146
Author(s):  
Jia Liu ◽  
Yinghua Zhang ◽  
Zhiming Bai ◽  
Zhian Huang ◽  
Yukun Gao ◽  
...  

An integrated tandem photoelectrochemical (PEC) cell, composed of a three-dimensional (3D) ZnO/CdS/NiFe layered double hydroxide (LDH) core/shell/hierarchical nanowire arrays (NWAs) photoanode and a [Formula: see text]-Cu2O photocathode, was designed for unassisted overall solar water splitting in this study. The optical and photoelectrochemical characteristics of ZnO-based photoanodes and Cu2O photocathode were investigated. The results show that ZnO/CdS/NiFe LDH nanostructures offer significantly enhanced performances with a photocurrent density reaching 5.8[Formula: see text]mA[Formula: see text][Formula: see text][Formula: see text]cm[Formula: see text] at 0.9[Formula: see text]V and an onset potential as early as 0.1[Formula: see text]V (versus RHE). The enhancement can be attributed to the existence of CdS nanoparticles (NPs) which boosts the light absorption in visible region and enhances charge separation. Moreover, the introduction of NiFe LDH nanoplates, with unique hierarchical mesoporous architecture, promotes electrochemical reactions by providing more active sites as co-catalyst. On the above basis, the ZnO/CdS/NiFe LDH–Cu2O two-electrode tandem cell system was established. At zero bias, the device shows a photocurrent density of 0.4[Formula: see text]mA[Formula: see text][Formula: see text][Formula: see text]cm[Formula: see text] along with the corresponding solar-to-hydrogen (STH) conversion efficiency reaching 0.50%. Our results indicate that the tandem PEC cells consisting of metal–oxide–semiconductor photoelectrodes based on Earth-abundant and low-cost materials hold promising application potential for overall solar water splitting.


2016 ◽  
Vol 9 (8) ◽  
pp. 2633-2643 ◽  
Author(s):  
Fanyu Ning ◽  
Mingfei Shao ◽  
Simin Xu ◽  
Yi Fu ◽  
Ruikang Zhang ◽  
...  

TiO2/graphene/NiFe-layered double hydroxide nanorod arrays were fabricated as highly efficient photoanodes for photoelectrochemical water splitting with simultaneously enhanced charge separation and water oxidation efficiency.


2017 ◽  
Vol 10 (8) ◽  
pp. 1820-1827 ◽  
Author(s):  
Luo Yu ◽  
Haiqing Zhou ◽  
Jingying Sun ◽  
Fan Qin ◽  
Fang Yu ◽  
...  

3D core–shell nanostructures of few-layer NiFe LDH nanosheets grown on Cu nanowires are fabricated toward highly efficient overall water splitting.


2016 ◽  
Vol 9 (2) ◽  
pp. 478-483 ◽  
Author(s):  
Yang Hou ◽  
Martin R. Lohe ◽  
Jian Zhang ◽  
Shaohua Liu ◽  
Xiaodong Zhuang ◽  
...  

A 3D ternary hybrid containing Co0.85Se nanosheet-array and NiFe-LDH grown on electrochemically exfoliated graphene was synthesized for highly-efficient overall water-splitting.’


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