Reductive amination using a combination of CaH2 and noble metal

RSC Advances ◽  
2015 ◽  
Vol 5 (3) ◽  
pp. 2292-2298 ◽  
Author(s):  
Carole Guyon ◽  
Eric Da Silva ◽  
Romain Lafon ◽  
Estelle Métay ◽  
Marc Lemaire
Keyword(s):  
Noble Metal ◽  
Reductive Amination ◽  
Calcium Hydride ◽  
Amination Reaction

Amines were prepared by a reductive amination reaction in the presence of calcium hydride and Pt/C.

scholarly journals Computational investigation of the control of the thermodynamics and microkinetics of the reductive amination reaction by solvent coordination and a co-catalyst

RSC Advances ◽  
2018 ◽  
Vol 8 (64) ◽  
pp. 36662-36674 ◽  
Author(s):  
Esra Boz ◽  
Nurcan Ş. Tüzün ◽  
Matthias Stein
Keyword(s):  
Tertiary Amine ◽  
Reductive Amination ◽  
Computational Investigation ◽  
Reaction Parameters ◽  
Co Catalyst ◽  
Amination Reaction ◽  
Green Production

Green production of tertiary amine from sustainable sources can be controlled by appropriate choice of reaction parameters identified by computational means.

N-Phenyl-Substituted Pyrrolidines, Piperidines and Azabicyclics by a Tandem Reduction-Double Reductive Amination Reaction.

ChemInform ◽  
2003 ◽  
Vol 34 (26) ◽  
Author(s):  
Richard A. Bunce ◽  
Derrick M. Herron ◽  
Jason R. Lewis ◽  
Sharadsrikar V. Kotturi
Keyword(s):  
Reductive Amination ◽  
Amination Reaction

scholarly journals Synthesis and structural characterization of amino-functionalized polysaccharides

2009 ◽  
Vol 7 (1) ◽  
pp. 66-73 ◽  
Author(s):  
Ioana Sisu ◽  
Valentina Udrescu ◽  
Corina Flangea ◽  
Sorin Tudor ◽  
Nicolae Dinca ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Thermal Analysis ◽  
Reductive Amination ◽  
Average Molecular Weight ◽  
Polymer Surface ◽  
Building Blocks ◽  
Collision Induced Dissociation ◽  
Amination Reaction ◽  
Composition And Structure

AbstractA variety of carbohydrates, in particular polysaccharides can be subjected to chemical modification to obtain derivatives with amphiphilic properties, which enable biochemical or biological reactions at the polymer surface. In the present work, a polydisperse maltodextrin mixture of average molecular weight 3000 was coupled with 1,6-hexamethylenediamine (HMD) via reductive amination reaction. Resulting products were characterized by thermal analysis and positive nanoelectrospray quadrupole time-of-flight (Q-TOF) mass spectrometry (MS) and tandem mass spectrometry (MS/MS). Both thermal analysis and MS screening confirmed the formation of the HMD-polysaccharide coupling products. Moreover, HMD-linked polysaccharide chains containing 2 to 26 glucose building blocks were identified by nanoESI Q-TOF MS. MS/MS fragmentation using collision-induced dissociation (CID) at low ion acceleration energies provided strong evidence for HMD-maltodextrin linkage formation and the set of sequence ions diagnostic for the composition and structure of a HMD-linked chain containing 18 glucose residues.

ChemInform Abstract: Diastereoselective Synthesis of Substituted Tetrahydroquinoline-4-carboxylic Esters by a Tandem Reduction-Reductive Amination Reaction.

ChemInform ◽  
2010 ◽  
Vol 32 (36) ◽  
pp. no-no
Author(s):  
Richard A. Bunce ◽  
Derrick M. Herron ◽  
Lara B. Johnson ◽  
Sharadsrikar V. Kotturi
Keyword(s):  
Reductive Amination ◽  
Diastereoselective Synthesis ◽  
Amination Reaction ◽  
Carboxylic Esters

A Sequential Palladium-Catalyzed Alder-Ene-Reductive Amination Reaction†

2005 ◽  
Vol 7 (11) ◽  
pp. 2237-2240 ◽  
Author(s):  
Christoph J. Kressierer ◽  
Thomas J. J. Müller
Keyword(s):  
Reductive Amination ◽  
Amination Reaction ◽  
Palladium Catalyzed

ChemInform Abstract: (.+-.)-2,3-Dialkyl-1,2,3,4-tetrahydroquinoline-3-carboxylic Esters by a Tandem Reduction-Reductive Amination Reaction.

ChemInform ◽  
2008 ◽  
Vol 39 (4) ◽  
Author(s):  
Richard A. Bunce ◽  
James E. Schammerhorn ◽  
LeGrande M. Slaughter
Keyword(s):  
Reductive Amination ◽  
Amination Reaction ◽  
Carboxylic Esters

Activity and Selectivity Control in Reductive Amination of Butyraldehyde over Noble Metal Catalysts

2005 ◽  
Vol 104 (1-2) ◽  
pp. 23-28 ◽  
Author(s):  
J. Bódis ◽  
L. Lefferts ◽  
T. E. Müller ◽  
R. Pestman ◽  
J. A. Lercher
Keyword(s):  
Noble Metal ◽  
Reductive Amination ◽  
Metal Catalysts ◽  
Noble Metal Catalysts ◽  
Selectivity Control

scholarly journals Reductive Amination Reaction for the Functionalization of Cellulose Nanocrystals

Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 5032
Author(s):  
Omar Hassan Hassan Omar ◽  
Rosa Giannelli ◽  
Erica Colaprico ◽  
Laura Capodieci ◽  
Francesco Babudri ◽  
...  
Keyword(s):  
Cellulose Nanocrystals ◽  
Reductive Amination ◽  
Photophysical Properties ◽  
New Materials ◽  
Light Emitting ◽  
Emission Profile ◽  
Organic Light ◽  
Amination Reaction ◽  
Functionalized Materials

Cellulose nanocrystals (CNCs) represent intriguing biopolymeric nanocrystalline materials, that are biocompatible, sustainable and renewable, can be chemically functionalized and are endowed with exceptional mechanical properties. Recently, studies have been performed to prepare CNCs with extraordinary photophysical properties, also by means of their functionalization with organic light-emitting fluorophores. In this paper, we used the reductive amination reaction to chemically bind 4-(1-pyrenyl)butanamine selectively to the reducing termini of sulfated or neutral CNCs (S_CNC and N_CNC) obtained from sulfuric acid or hydrochloric acid hydrolysis. The functionalization reaction is simple and straightforward, and it induces the appearance of the typical pyrene emission profile in the functionalized materials. After a characterization of the new materials performed by ATR-FTIR and fluorescence spectroscopies, we demonstrate luminescence quenching of the decorated N_CNC by copper (II) sulfate, hypothesizing for these new functionalized materials an application in water purification technologies.

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