Spectacular photocatalytic hydrogen evolution using metal-phosphide/CdS hybrid catalysts under sunlight irradiation

2015 ◽  
Vol 51 (41) ◽  
pp. 8708-8711 ◽  
Author(s):  
Shuang Cao ◽  
Yong Chen ◽  
Chuan-Jun Wang ◽  
Xiao-Jun Lv ◽  
Wen-Fu Fu
Keyword(s):  
Photocatalytic Activity ◽  
Transition Metal ◽  
Hydrogen Evolution ◽  
Acidic Media ◽  
Metal Phosphide ◽  
Sunlight Irradiation ◽  
Photocatalytic Hydrogen Evolution ◽  
Hybrid Catalysts ◽  
Transition Metal Phosphide ◽  
Excellent Stability

Transition metal phosphide (CoP,Ni2P,Cu3P)/CdS hybrid catalysts were applied to heterogeneous photocatalytic hydrogen evolution and exhibited splendid photocatalytic activity with a H2-production rate of up to 254 000 μmol h−1 g−1 and excellent stability in aqueous acidic media.

Transition metal phosphide of nickel and cobalt modified Zn0.5Cd0.5S for efficient photocatalytic hydrogen evolution with visible light irradiation

2021 ◽  
Author(s):  
Linying Hu ◽  
Jing Xu ◽  
Shun Yang ◽  
Zhongyi Tan ◽  
Lijuan Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Hydrogen Evolution ◽  
Noble Metal ◽  
Visible Light Irradiation ◽  
Environmentally Friendly ◽  
Light Irradiation ◽  
Metal Phosphide ◽  
Photocatalytic Hydrogen Evolution ◽  
Transition Metal Phosphide

Transition metal phosphide (TMPs), as environmentally friendly non-noble metal cocatalyst, play a key role in promoting photocatalytic hydrogen evolution. In this work, three metal phosphating compounds (NiCoP, Ni2P, and Co2P)...

Mechanisms for hydrogen evolution on transition metal phosphide catalysts and a comparison to Pt(111)

2019 ◽  
Vol 21 (44) ◽  
pp. 24489-24498 ◽  
Author(s):  
Chenyang Li ◽  
Hao Gao ◽  
Wan Wan ◽  
Tim Mueller
Keyword(s):  
Monte Carlo ◽  
Transition Metal ◽  
Monte Carlo Simulations ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Surface Coverage ◽  
Cluster Expansions ◽  
Metal Phosphide ◽  
Transition Metal Phosphide ◽  
Model Transition

Cluster expansions and Monte Carlo simulations provide insights into the mechanisms for the hydrogen evolution reaction and the effects of potential and surface coverage on Pt(111) and model transition metal phosphide surfaces.

Sacrificial Species Approach to Designing Robust Transition Metal Phosphide Cathodes for Alkaline Water Electrolysis in Discontinuous Operation

2021 ◽  
Author(s):  
Ik-Sun Kim ◽  
Hyun-Seok Cho ◽  
MinJoong Kim ◽  
Hyung-Jung Oh ◽  
Sang-Yeon Lee ◽  
...  
Keyword(s):  
Transition Metal ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Water Electrolysis ◽  
Alkaline Water Electrolysis ◽  
Metal Phosphide ◽  
Alkaline Water ◽  
Electrolysis Cells ◽  
Transition Metal Phosphide

The degradation of amorphous cobalt phosphides (CoPx) as electrocatalyst for hydrogen evolution reaction (HER) is studied in the discontinuous operation of alkaline water electrolysis cells (AWEs). Although amorphous CoPx shows...

A general approach to the synthesis of transition metal phosphide nanoarrays on MXene nanosheets for pH-universal hydrogen evolution and alkaline overall water splitting

2020 ◽  
Vol 8 (28) ◽  
pp. 14234-14242 ◽  
Author(s):  
Liang Yan ◽  
Bing Zhang ◽  
Shangyou Wu ◽  
Jianlin Yu
Keyword(s):  
Transition Metal ◽  
Hydrogen Evolution ◽  
Water Splitting ◽  
Noble Metal ◽  
Metal Phosphide ◽  
Highly Efficient ◽  
Overall Water Splitting ◽  
Bifunctional Electrocatalysts ◽  
Transition Metal Phosphide

Exploring highly efficient, stable, and non-noble-metal bifunctional electrocatalysts for overall water splitting is greatly desired but still remains an ongoing challenge.

General Method for Synthesizing Transition-Metal Phosphide/N-Doped Carbon Nanomaterials for Hydrogen Evolution

Langmuir ◽  
2019 ◽  
Vol 35 (28) ◽  
pp. 9161-9168 ◽  
Author(s):  
Lunqiang Jin ◽  
Xiang Zhang ◽  
Weifeng Zhao ◽  
Shengqiu Chen ◽  
Zhenqiang Shi ◽  
...  
Keyword(s):  
Transition Metal ◽  
Hydrogen Evolution ◽  
Carbon Nanomaterials ◽  
Metal Phosphide ◽  
Transition Metal Phosphide ◽  
General Method

Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends

2015 ◽  
Vol 8 (10) ◽  
pp. 3022-3029 ◽  
Author(s):  
Jakob Kibsgaard ◽  
Charlie Tsai ◽  
Karen Chan ◽  
Jesse D. Benck ◽  
Jens K. Nørskov ◽  
...  
Keyword(s):  
Transition Metal ◽  
Hydrogen Evolution ◽  
Hydrogen Adsorption ◽  
Free Energies ◽  
Metal Phosphide ◽  
Metal Phosphides ◽  
Transition Metal Phosphide ◽  
Transition Metal Phosphides

A volcano relationship exists between hydrogen evolution activities and hydrogen adsorption free energies for transition metal phosphides. We further predict and confirm that Fe0.5Co0.5P exhibits the highest activity.

scholarly journals Correction: Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction

2016 ◽  
Vol 45 (6) ◽  
pp. 1781-1781 ◽  
Author(s):  
Yanmei Shi ◽  
Bin Zhang
Keyword(s):  
Transition Metal ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Metal Phosphide ◽  
Recent Advances ◽  
Nanomaterials Synthesis ◽  
Transition Metal Phosphide

Correction for ‘Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction’ by Yanmei Shi et al., Chem. Soc. Rev., 2016, DOI: 10.1039/c5cs00434a.

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