The Soret absorption band of isolated chlorophyll a and b tagged with quaternary ammonium ions

2015 ◽  
Vol 17 (39) ◽  
pp. 25793-25798 ◽  
Author(s):  
Mark H. Stockett ◽  
Lihi Musbat ◽  
Christina Kjær ◽  
Jørgen Houmøller ◽  
Yoni Toker ◽  
...  

The true colors of chlorophyll a and b, isolated in vacuo, are revealed from a combination of gas-phase ion spectroscopy and TD-DFT calculations.

2016 ◽  
Vol 120 (47) ◽  
pp. 12105-12110 ◽  
Author(s):  
Christina Kjær ◽  
Mark H. Stockett ◽  
Bjarke M. Pedersen ◽  
Steen Brøndsted Nielsen

2018 ◽  
Vol 122 (12) ◽  
pp. 3211-3217 ◽  
Author(s):  
Christina Kjær ◽  
James M. Lisy ◽  
Steen Brøndsted Nielsen

2016 ◽  
Vol 145 (10) ◽  
pp. 104303 ◽  
Author(s):  
M. H. Stockett ◽  
J. Houmøller ◽  
S. Brøndsted Nielsen

2020 ◽  
Author(s):  
Oisin Shiels ◽  
P. D. Kelly ◽  
Cameron C. Bright ◽  
Berwyck L. J. Poad ◽  
Stephen Blanksby ◽  
...  

<div> <div> <div> <p>A key step in gas-phase polycyclic aromatic hydrocarbon (PAH) formation involves the addition of acetylene (or other alkyne) to σ-type aromatic radicals, with successive additions yielding more complex PAHs. A similar process can happen for N- containing aromatics. In cold diffuse environments, such as the interstellar medium, rates of radical addition may be enhanced when the σ-type radical is charged. This paper investigates the gas-phase ion-molecule reactions of acetylene with nine aromatic distonic σ-type radical cations derived from pyridinium (Pyr), anilinium (Anl) and benzonitrilium (Bzn) ions. Three isomers are studied in each case (radical sites at the ortho, meta and para positions). Using a room temperature ion trap, second-order rate coefficients, product branching ratios and reaction efficiencies are reported. </p> </div> </div> </div>


Author(s):  
Ying Zhao ◽  
Emma Rostal Sørensen ◽  
Thomas Toft Lindkvist ◽  
Christina Kjær ◽  
Mogens Brøndsted Nielsen ◽  
...  
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