Slow magnetic relaxation in mononuclear seven-coordinate cobalt(ii) complexes with easy plane anisotropy

2015 ◽  
Vol 44 (25) ◽  
pp. 11482-11490 ◽  
Author(s):  
Lei Chen ◽  
Shu-Yang Chen ◽  
Yi-Chen Sun ◽  
Yu-Mei Guo ◽  
Lu Yu ◽  
...  
Keyword(s):  
Magnetic Relaxation ◽  
Slow Relaxation ◽  
Positive Zero ◽  
Pentagonal Bipyramid ◽  
Zero Field ◽  
Relaxation Behaviour ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Plane Anisotropy ◽  
Slow Magnetic Relaxation

Two mononuclear pentagonal bipyramid cobalt(ii) complexes with positive zero-field splitting D values were demonstrated to exhibit field-induced slow relaxation behaviour.

Positive zero-field splitting and unexpected slow magnetic relaxation in the magneto-chemical calibrant HgCo(NCS)4

2021 ◽  
Vol 50 (10) ◽  
pp. 3468-3472
Author(s):  
Roman Boča ◽  
Ján Titiš ◽  
Cyril Rajnák ◽  
J. Krzystek
Keyword(s):  
Magnetic Field ◽  
External Magnetic Field ◽  
Magnetic Relaxation ◽  
Positive Zero ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Zero Field Splitting Parameter ◽  
Slow Magnetic Relaxation ◽  
Splitting Parameter

Magnetochemical standard HgCo(NCS)4 with positive zero-field splitting parameter D displays a slow magnetic relaxation strongly dependent upon the external magnetic field.

Correlating the axial Zero Field Splitting with the slow magnetic relaxation in GdIII SIMs

2021 ◽  
Author(s):  
Júlia Mayans ◽  
Albert Escuer
Keyword(s):  
Magnetic Relaxation ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Slow Magnetic Relaxation

A possible relation between the value of the axial Zero Field Splitting and the occurrence of field-induced slow magnetic relaxation has been established for a new gadolinium(iii) compound.

scholarly journals Effects of coordination sphere on unusually large zero field splitting and slow magnetic relaxation in trigonally symmetric molecules

2018 ◽  
Vol 9 (48) ◽  
pp. 9018-9026 ◽  
Author(s):  
Kelsey A. Schulte ◽  
Kuduva R. Vignesh ◽  
Kim R. Dunbar
Keyword(s):  
Water Molecule ◽  
Coordination Sphere ◽  
Magnetic Relaxation ◽  
Magnetic Behavior ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Slow Magnetic Relaxation

Coordination of a water molecule results in drastic effects on the magnetic behavior of a series of trigonal monopyramidal and bipyramidal compounds.

scholarly journals Slow Magnetic Relaxation in a CoII-YIIISingle-Ion Magnet with Positive Axial Zero-Field Splitting

2013 ◽  
Vol 52 (35) ◽  
pp. 9130-9134 ◽  
Author(s):  
Enrique Colacio ◽  
José Ruiz ◽  
Eliseo Ruiz ◽  
Eduard Cremades ◽  
J. Krzystek ◽  
...  
Keyword(s):  
Magnetic Relaxation ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Slow Magnetic Relaxation

scholarly journals Slow Magnetic Relaxation in a Co II –Y III Single‐Ion Magnet with Positive Axial Zero‐Field Splitting

2013 ◽  
Vol 125 (35) ◽  
pp. 9300-9304 ◽  
Author(s):  
Enrique Colacio ◽  
José Ruiz ◽  
Eliseo Ruiz ◽  
Eduard Cremades ◽  
J. Krzystek ◽  
...  
Keyword(s):  
Magnetic Relaxation ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Slow Magnetic Relaxation

Slow Magnetic Relaxation Induced by a Large Transverse Zero-Field Splitting in a MnIIReIV(CN)2 Single-Chain Magnet

2012 ◽  
Vol 134 (17) ◽  
pp. 7521-7529 ◽  
Author(s):  
Xiaowen Feng ◽  
Junjie Liu ◽  
T. David Harris ◽  
Stephen Hill ◽  
Jeffrey R. Long
Keyword(s):  
Magnetic Relaxation ◽  
Zero Field ◽  
Single Chain ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Slow Magnetic Relaxation

scholarly journals Large Positive Zero-Field Splitting in the Cluster Magnet Ba3CeRu2O9

2019 ◽  
Vol 141 (25) ◽  
pp. 9928-9936 ◽  
Author(s):  
Qiang Chen ◽  
Shiyu Fan ◽  
Keith M. Taddei ◽  
Matthew B. Stone ◽  
Alexander I. Kolesnikov ◽  
...  
Keyword(s):  
Positive Zero ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting

Proof of Large Positive Zero-Field Splitting in a Ru25+Paddlewheel

2005 ◽  
Vol 127 (36) ◽  
pp. 12691-12696 ◽  
Author(s):  
Wei-Zhong Chen ◽  
F. Albert Cotton ◽  
Naresh S. Dalal ◽  
Carlos A. Murillo ◽  
Chris M. Ramsey ◽  
...  
Keyword(s):  
Positive Zero ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting

Slow magnetic relaxation in Dy2 and Dy4 complexes of a versatile, trifunctional polydentate N,O-ligand

2019 ◽  
Vol 48 (38) ◽  
pp. 14269-14278 ◽  
Author(s):  
Muhammad U. Anwar ◽  
Ahmed Al-Harrasi ◽  
Jeremy M. Rawson ◽  
Emma L. Gavey ◽  
Jeffery Regier ◽  
...  
Keyword(s):  
Magnetic Relaxation ◽  
Slow Relaxation ◽  
Zero Field ◽  
Slow Magnetic Relaxation

A binuclear DyIII complex exhibits slow relaxation of magnetization under an applied dc field, while its tetranuclear counterpart exhibits “true” zero-field SMM behaviour.

Positive zero-field splitting in a hexacoordinate nickel(II) complex

2013 ◽  
Vol 32 ◽  
pp. 9-11 ◽  
Author(s):  
Alena Packová ◽  
Jozef Miklovič ◽  
Ján Titiš ◽  
Marián Koman ◽  
Roman Boča
Keyword(s):  
Positive Zero ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting
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