Merging open metal sites and Lewis basic sites in a NbO-type metal–organic framework for improved C2H2/CH4 and CO2/CH4 separation

2015 ◽  
Vol 44 (33) ◽  
pp. 14823-14829 ◽  
Author(s):  
Chengling Song ◽  
Jiayi Hu ◽  
Yajing Ling ◽  
Yunlong Feng ◽  
De-Li Chen ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Gas Mixtures ◽  
Basic Sites ◽  
Basic Nitrogen ◽  
Nitrogen Donor ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Copper Sites ◽  
Organic Framework

A new NbO-type metal–organic framework ZJNU-47a incorporating Lewis acidic copper sites and Lewis basic nitrogen donor sites exhibits better performance than the isostructural NOTT-101a in the separation of C2H2/CH4 and CO2/CH4 gas mixtures at room temperature.

A microporous yttrium metal–organic framework of an unusual nia topology for high adsorption selectivity of C2H2and CO2over CH4at room temperature

2017 ◽  
Vol 1 (10) ◽  
pp. 1982-1988 ◽  
Author(s):  
Kang Liu ◽  
Xu Li ◽  
Dingxuan Ma ◽  
Yi Han ◽  
Baiyan Li ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Selectivity ◽  
Basic Sites ◽  
Metal Organic ◽  
Organic Framework

A new microporous yttrium MOF Y-H3TDPAT with Lewis basic sites on the pore surfaces was hydrothermally synthesized and structurally characterized as an unusualniatopology.

A Metal-Organic Framework with Optimized Open Metal Sites and Pore Spaces for High Methane Storage at Room Temperature

2011 ◽  
Vol 123 (14) ◽  
pp. 3236-3239 ◽  
Author(s):  
Zhiyong Guo ◽  
Hui Wu ◽  
Gadipelli Srinivas ◽  
Yaming Zhou ◽  
Shengchang Xiang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Methane Storage ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

A Metal-Organic Framework with Optimized Open Metal Sites and Pore Spaces for High Methane Storage at Room Temperature

2011 ◽  
Vol 50 (14) ◽  
pp. 3178-3181 ◽  
Author(s):  
Zhiyong Guo ◽  
Hui Wu ◽  
Gadipelli Srinivas ◽  
Yaming Zhou ◽  
Shengchang Xiang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Methane Storage ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

A bifunctional metal–organic framework featuring the combination of open metal sites and Lewis basic sites for selective gas adsorption and heterogeneous cascade catalysis

2016 ◽  
Vol 4 (39) ◽  
pp. 15240-15246 ◽  
Author(s):  
Hongming He ◽  
Fuxing Sun ◽  
Briana Aguila ◽  
Jason A. Perman ◽  
Shengqian Ma ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Basic Sites ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework ◽  
Cascade Catalysis

A bifunctional MOF featuring the combination of open metal sites (Zn2+) and Lewis basic sites (–NH2) has been constructed for selective gas adsorption and heterogeneous cascade catalysis.

Triple Framework Interpenetration and Immobilization of Open Metal Sites within a Microporous Mixed Metal–Organic Framework for Highly Selective Gas Adsorption

2012 ◽  
Vol 51 (9) ◽  
pp. 4947-4953 ◽  
Author(s):  
Zhangjing Zhang ◽  
Shengchang Xiang ◽  
Kunlun Hong ◽  
Madhab, C. Das ◽  
Hadi D. Arman ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Mixed Metal ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework
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