Preparation and crystal structure of K2Ce(PO4)2: a new complex phosphate of Ce(iv) having structure with one-dimensional channels

2016 ◽  
Vol 45 (3) ◽  
pp. 980-991 ◽  
Author(s):  
Samatha Bevara ◽  
S. Nagabhusan Achary ◽  
Sadequa J. Patwe ◽  
Anil K. Sinha ◽  
Avesh Kumar Tyagi

Synthesis and crystal structure of K2Ce(PO4)2, which is a new complex phosphate with Ce4+.

Author(s):  
Glen G. Briand ◽  
Andreas Decken ◽  
Courtney M. Dickie ◽  
Gregory MacNeil

The dinuclear title compound, [In2(CH3)2(C7H7S)4] or [Me(2-MeC6H4S)In-μ-(2-MeC6H4S)2InMe(2-MeC6H4S)], was prepared from the 1:2 reaction of Me3In and 2-MeC6H4SH in toluene. Its crystal structure exhibits a four-membered In2S2ring coreviabridging (2-MeC6H4S) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to theaaxisviaintermolecular In...S contacts. The In atoms are then in distorted trigonal–bipyramidal CS4bonding environments.


ChemInform ◽  
2003 ◽  
Vol 34 (9) ◽  
Author(s):  
Qing-An Zhang ◽  
Yumiko Nakamura ◽  
Ken-ich Oikawa ◽  
Takashi Kamiyama ◽  
Etsuo Akiba

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