An open framework crystal structure and physical properties of RbCuAl(PO4)2

2016 ◽  
Vol 45 (6) ◽  
pp. 2598-2604 ◽  
Author(s):  
Olga V. Yakubovich ◽  
Galina V. Kiriukhina ◽  
Olga V. Dimitrova ◽  
Elena A. Zvereva ◽  
Larisa V. Shvanskaya ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Physical Properties ◽  
Single Crystals ◽  
Spontaneous Magnetization ◽  
Framework Structure ◽  
Hydrothermal Route ◽  
Open Framework ◽  
Lower Temperature ◽  
3D Framework

Single crystals of the RbCuAl(PO4)2 compound with an open 3D framework structure were obtained by a hydrothermal route. The compound orders antiferromagnetically at TN = 10.5 K and exhibits spontaneous magnetization at lower temperature.

Crystal chemistry and physical properties of the A2M3(H2O)2[B4P6O24(OH)2] (A = Cs, Rb; M = Ni, Cu, (Ni, Fe)) borophosphate family

2019 ◽  
Vol 48 (24) ◽  
pp. 8835-8842
Author(s):  
Larisa Shvanskaya ◽  
Olga Yakubovich ◽  
Lyubov Melchakova ◽  
Anna Ivanova ◽  
Alexander Vasiliev
Keyword(s):  
Crystal Structure ◽  
Thermal Properties ◽  
Physical Properties ◽  
Crystal Chemistry ◽  
3D Framework

A flexible 3D framework in the A2M3(H2O)2[B4P6O24(OH)2] (A = Cs, Rb; M = Ni, Cu, (Ni, Fe)) borophosphates: synthesis, crystal structure, magnetic and thermal properties.

Crystal structure and physical properties of EuMo6S8 single crystals at ambient pressure

1986 ◽  
Vol 63 (1) ◽  
pp. 62-69 ◽  
Author(s):  
O. Peña ◽  
R. Horyn ◽  
C. Geantet ◽  
P. Gougeon ◽  
J. Padiou ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Physical Properties ◽  
Single Crystals ◽  
Ambient Pressure

Synthesis, crystal structure and luminescence properties of eight new lanthanide carboxyphosphonates with a 3D framework structure

2010 ◽  
Vol 34 (11) ◽  
pp. 2429 ◽  
Author(s):  
Na Zhang ◽  
Zhengang Sun ◽  
Yanyu Zhu ◽  
Jing Zhang ◽  
Lei Liu ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Luminescence Properties ◽  
Framework Structure ◽  
3D Framework

scholarly journals Crystal structure of magnesium copper(II) bis[orthophosphate(V)] monohydrate

2015 ◽  
Vol 71 (1) ◽  
pp. 55-57 ◽  
Author(s):  
Jamal Khmiyas ◽  
Abderrazzak Assani ◽  
Mohamed Saadi ◽  
Lahcen El Ammari
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Single Crystals ◽  
Water Molecules ◽  
Framework Structure ◽  
Hydrothermal Conditions ◽  
The Third ◽  
Hydrogen Bonding Interactions

Single crystals of magnesium copper(II) bis[orthophosphate(V)] monohydrate, Mg1.65Cu1.35(PO4)2·H2O, were grown under hydrothermal conditions. The crystal structure is formed by three types of cationic sites and by two unique (PO4)3−anions. One site is occupied by Cu2+, the second site by Mg2+and the third site by a mixture of the two cations with an Mg2+:Cu2+occupancy ratio of 0.657 (3):0.343 (3). The structure is built up from more or less distorted [MgO6] and [(Mg/Cu)O5(H2O)] octahedra, [CuO5] square-pyramids and regular PO4tetrahedra, leading to a framework structure. Within this framework, two types of layers parallel to (-101) can be distinguished. The first layer is formed by [Cu2O8] dimers linked to PO4tetrahedraviacommon edges. The second, more corrugated layer results from the linkage between [(Cu/Mg)2O8(H2O)2] dimers and [MgO6] octahedra by common edges. The PO4units link the two types of layers, leaving space for channels parallel [101], into which the H atoms of the water molecules protrude. The latter are involved in O—H...O hydrogen-bonding interactions (one bifurcated) with framework O atoms across the channels.

Metallic barrelane: crystal structure, physical properties and bonding analysis of La16Al13

2005 ◽  
Vol 220 (2/3) ◽  
Author(s):  
Rainer Niewa ◽  
Martin Kirchner ◽  
Hui Zhang ◽  
Walter Schnelle ◽  
Yuri Grin
Keyword(s):  
Crystal Structure ◽  
Intermetallic Compound ◽  
Physical Properties ◽  
Single Crystals ◽  
Bonding Analysis

AbstractSingle crystals of the new intermetallic compound La

Crystal structure and physical properties of EuMo6S8 single crystals

Physica B+C ◽  
1985 ◽  
Vol 135 (1-3) ◽  
pp. 333-335
Author(s):  
O. Peña ◽  
R. Horyn ◽  
J. Padiou ◽  
P. Gougeon ◽  
M. Sergent
Keyword(s):  
Crystal Structure ◽  
Physical Properties ◽  
Single Crystals

scholarly journals Crystal structure of SrCo4(OH)(PO4)3, a new hydroxyphosphate

2020 ◽  
Vol 76 (7) ◽  
pp. 1022-1026
Author(s):  
Fatima-Zahra Cherif ◽  
Mhamed Taibi ◽  
Ali Boukhari ◽  
Jilali Aride ◽  
Abderrazzak Assani ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Infrared Spectroscopy ◽  
Hydrogen Bonds ◽  
Single Crystals ◽  
Title Compound ◽  
Crystal Packing ◽  
Framework Structure ◽  
Hydrothermal Conditions

Single crystals of strontium tetracobalt tris(orthophosphate) hydroxide, SrCo4(OH)(PO4)3, were grown serendipitously under hydrothermal conditions at 473 K. The crystal structure consists of undulating chains of edge-sharing [CoO6] octahedra that are linked into (010) layers by common vertices between chains. Adjacent layers are linked along [010] into a framework structure by tetrahedral [CoO4] units and by PO4 tetrahedra. The framework delimits channels extending along [100] in which the eleven-coordinate strontium cations are situated. Bifurcated O—H...O hydrogen bonds of weak strengths consolidate the crystal packing. The title compound was also characterized by infrared spectroscopy.

scholarly journals New Ag8PtO6: synthesis, crystal structure, physical properties and theoretical analyses

2019 ◽  
Vol 48 (15) ◽  
pp. 5058-5063 ◽  
Author(s):  
Gohil Singh Thakur ◽  
Hans Reuter ◽  
Helge Rosner ◽  
Gerhard H. Fecher ◽  
Claudia Felser ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Physical Properties ◽  
Framework Structure ◽  
Theoretical Analyses

Ag8PtO6 is the first silver platinate and features a framework structure consisting of “isolated” PtO6 octahedra and O–Ag–O linkers.

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