scholarly journals Electronic communication in phosphine substituted bridged dirhenium complexes – clarifying ambiguities raised by the redox non-innocence of the C4H2- and C4-bridges

2016 ◽  
Vol 45 (13) ◽  
pp. 5783-5799 ◽  
Author(s):  
Yan Li ◽  
Olivier Blacque ◽  
Thomas Fox ◽  
Sandra Luber ◽  
Walther Polit ◽  
...  
Keyword(s):  
Electronic Communication ◽  
Closed Shell ◽  
Shell Structures ◽  
Rhenium Complexes ◽  
Dirhenium Complexes

Dinuclear rhenium complexes with C4H2- or C4- bridges can show open or closed shell structures.

scholarly journals Organometallphosphin-substituierte Übergangsmetallkomplexe, XXVII [1] Reaktionen von Pentacarbonylmangan-und Pentacarbonylrheniumbromid mit Organoelement(rVb)phosphinen / Organometalphosphine-Substituted Transition Metal Complexes, XXVII [1] Reactions of Pentacarbonylmanganese-and Pentacarbonylrheniumbromide with Organoelement(IVb) Phosphines

1981 ◽  
Vol 36 (6) ◽  
pp. 708-712 ◽  
Author(s):  
Herbert Schumann ◽  
Heinrich Neumann
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Mössbauer Spectra ◽  
Rhenium Complexes ◽  
Tert Butyl ◽  
Mossbauer Spectra ◽  
Dirhenium Complexes

Abstract The reactions of pentacarbonyl manganese bromide and pentacarbonyl rhenium bromide with di(tert-butyl)trimethylsilyl phosphine, teri-butyl-bis(trimethylsilyl)-, -(germyl)-, -(stannyl) phosphine, as well as with tris(trimethylsilyl)-, -(germyl)-, and -(stannyl) phosphine result in the elimination of one CO ligand and the formation either of corresponding bromo-tetracarbonyl(organometalphosphine)manganese or -rhenium complexes or of corresponding octacarbonyl-bis(μ-organometalphosphido)dimanganese or -dirhenium complexes. The IR, NMR, and Mössbauer spectra are reported and discussed.

Synthesis of Metallic Nanoparticles Using Closed-Shell Structures as Templates

2018 ◽  
Vol 13 (4) ◽  
pp. 362-372 ◽  
Author(s):  
Li Qiu ◽  
Ryan McCaffrey ◽  
Wei Zhang
Keyword(s):  
Metallic Nanoparticles ◽  
Closed Shell ◽  
Shell Structures

Closed-shell structures and the building game

1987 ◽  
Vol 141 (6) ◽  
pp. 478-484 ◽  
Author(s):  
David J. Wales
Keyword(s):  
Closed Shell ◽  
Shell Structures

Diradical ring closing reactions displaying Woodward–Hoffmann behaviour and torquoselectivity

RSC Advances ◽  
2015 ◽  
Vol 5 (38) ◽  
pp. 30405-30408 ◽  
Author(s):  
Roberto Villar López ◽  
Olalla Nieto Faza ◽  
Carlos Silva López
Keyword(s):  
Closed Shell ◽  
Shell Structures

The applicability of the Woodward–Hoffmann rules seems to expand beyond classical closed shell structures.

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