Synthesis and characterization of bis(amidate) rare-earth metal amides and their application in catalytic addition of amines to carbodiimides

2015 ◽  
Vol 39 (10) ◽  
pp. 7667-7671 ◽  
Author(s):  
Hao Cheng ◽  
Yang Xiao ◽  
Chengrong Lu ◽  
Bei Zhao ◽  
Yaorong Wang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Synthesis And Characterization ◽  
Metal Amides ◽  
Catalytic Addition

Five bis(amidate) rare-earth metal amides were successfully employed in guanidination, and the Nd-based catalyst showed the highest reactivity.

Synthesis and characterization of 2-t-butylimino-functionalized indolyl rare-earth metal amido complexes for the catalytic addition of terminal alkynes to carbodiimides: the dimeric complexes with the alkynide species in the μ–η1:η2 bonding modes

2019 ◽  
Vol 48 (29) ◽  
pp. 11094-11102 ◽  
Author(s):  
Zhijun Feng ◽  
Zeming Huang ◽  
Shaowu Wang ◽  
Yun Wei ◽  
Shuangliu Zhou ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Catalytic Reaction ◽  
Earth Metal ◽  
Synthesis And Characterization ◽  
Terminal Alkynes ◽  
Amido Complexes ◽  
Dimeric Complexes ◽  
Catalytic Addition

Dimeric complexes [(μ–η1:η2-RCC)REL2]2 (L = 2-(tBuNCH)C8H5N), with alkynyl in the μ–η1:η2 modes, were isolated in the study of the catalytic reaction.

Synthesis and characterization of bridged bis(amidato) rare earth metal amides and their applications in C–N bond formation reactions

2016 ◽  
Vol 45 (9) ◽  
pp. 3880-3887 ◽  
Author(s):  
Bei Zhao ◽  
Yang Xiao ◽  
Dan Yuan ◽  
Chengrong Lu ◽  
Yingming Yao
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Bond Formation ◽  
Earth Metal ◽  
Synthesis And Characterization ◽  
Catalytic Activities ◽  
Metal Amides ◽  
Direct Amidation ◽  
Bond Formation Reactions

Eight bis(amidato) rare-earth metal amides were successfully synthesized and well characterized, which exhibited high catalytic activities in both the direct amidation of aldehydes and the addition of amines with carbodiimine.

scholarly journals Synthesis and Characterization of Heterobimetallic Oxo-Bridged Aluminum–Rare Earth Metal Complexes

2011 ◽  
Vol 50 (16) ◽  
pp. 7453-7459 ◽  
Author(s):  
Jingjun Hao ◽  
Jianfeng Li ◽  
Chunming Cui ◽  
Herbert W. Roesky
Keyword(s):  
Rare Earth ◽  
Metal Complexes ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Synthesis And Characterization ◽  
Rare Earth Metal Complexes
Sign in / Sign up

Export Citation Format

Share Document