scholarly journals One-pot vinylogous aldol addition of β,γ-unsaturated esters under mild conditions

2015 ◽  
Vol 39 (7) ◽  
pp. 5121-5123 ◽  
Author(s):  
İsmail Akçok ◽  
Ali Çağır

A new methodology for the addition of β,γ-unsaturated esters to aldehydes was developed in a TMSCl, Ag2CO3, and TBAF mixture.

2016 ◽  
Vol 14 (8) ◽  
pp. 2390-2394 ◽  
Author(s):  
Gui-Xin Cai ◽  
Jing Wen ◽  
Ting-Ting Lai ◽  
Dan Xie ◽  
Cheng-He Zhou

A K2CO3-catalyzed one-pot protocol involving sequential C–C bond formation and cleavage of aromatic β-diketones with α,β-unsaturated esters is developed to obtain 1,5-ketoesters, proceeding smoothly under mild conditions in up to 98% isolated yield.


2017 ◽  
Vol 19 (20) ◽  
pp. 4838-4848 ◽  
Author(s):  
Gang Wang ◽  
Yiming Xu ◽  
Suojiang Zhang ◽  
Zengxi Li ◽  
Chunshan Li

An ionic liquid catalyzed probase method for unsaturated ester synthesis under mild conditions was reported.


2021 ◽  
Author(s):  
Pagasukon Mekrattanachai ◽  
Lei Zhu ◽  
Naruemon Setthaya ◽  
Chakkresit Chindawong ◽  
Wei Guo Song

Author(s):  
Philipp Natho ◽  
Zeyu Yang ◽  
Lewis Allen ◽  
Juliette Rey ◽  
Andrew J P White ◽  
...  

A transition-metal-free strategy for the synthesis of 2-(cyclobut-1-en-1-yl)-1H-indoles under mild conditions is described herein. A series of substituted 2-(cyclobut-1-en-1-yl)-1H-indoles are accessed by a one-pot cyclobutenylation/deprotection cascade from N-Boc protected indoles....


2007 ◽  
Vol 48 (10) ◽  
pp. 1809-1811 ◽  
Author(s):  
Christopher A. Simoneau ◽  
Alexis M. Strohl ◽  
Bruce Ganem

2017 ◽  
Vol 4 (8) ◽  
pp. 1636-1639 ◽  
Author(s):  
Bin Cheng ◽  
Bian Bao ◽  
Yanhe Chen ◽  
Ning Wang ◽  
Yun Li ◽  
...  

A new route to arylhydrazides involving the reaction of two highly active intermediates, the 1,3-zwitterion generated in situ from the Mitsunobu reagent and arynes, under mild conditions has been developed.


2006 ◽  
Vol 118 (17) ◽  
pp. 2832-2834 ◽  
Author(s):  
Yoichiro Kuninobu ◽  
Yuta Nishina ◽  
Makoto Shouho ◽  
Kazuhiko Takai

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