Synthesis and self-assembly of a fluorine-containing amphiphilic graft copolymer bearing a perfluorocyclobutyl aryl ether-based backbone and poly(acrylic acid) side chains

2015 ◽  
Vol 6 (23) ◽  
pp. 4309-4318 ◽  
Author(s):  
Hao Liu ◽  
Sen Zhang ◽  
Chun Feng ◽  
Yongjun Li ◽  
Guolin Lu ◽  
...  

Fluorine-containing amphiphilic graft copolymers made of a semi-fluorinated PMBTFVB backbone and hydrophilic PAA side chains were synthesized by the combination of thermal cycloaddition polymerization and ATRP.

RSC Advances ◽  
2015 ◽  
Vol 5 (50) ◽  
pp. 39668-39676 ◽  
Author(s):  
Guolin Lu ◽  
Hao Liu ◽  
Haifeng Gao ◽  
Chun Feng ◽  
Yongjun Li ◽  
...  

Amphiphilic graft copolymers bearing a hydrophobic PMBTFVB backbone and hydrophilic PEG side chains were synthesized by Williamson reaction through the grafting-onto strategy.


RSC Advances ◽  
2015 ◽  
Vol 5 (91) ◽  
pp. 74947-74952 ◽  
Author(s):  
Guolin Lu ◽  
Xiaojun Jiang ◽  
Yongjun Li ◽  
Xuliang Lv ◽  
Xiaoyu Huang

This article reports the synthesis of an amphiphilic graft copolymer containing a perfluorocyclobutyl (PFCB) aryl ether-based backbone and poly(N-isopropylacrylamide) side chains by a combination of thermal step-growth cycloaddition polymerization and atom transfer radical polymerization (ATRP).


2014 ◽  
Vol 5 (17) ◽  
pp. 4915-4925 ◽  
Author(s):  
Xiuyu Jiang ◽  
Xue Jiang ◽  
Guolin Lu ◽  
Chun Feng ◽  
Xiaoyu Huang

This paper reports the first synthesis of well-defined amphiphilic graft copolymers, consisting of a hydrophilic poly(2-hydroxyethyl acrylate) (PHEA) backbone and hydrophobic polystyrene side chains, by the combination of RAFT polymerization, ATRP, and the grafting-from strategy.


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