PtAu alloy nanoparticles supported on thermally expanded graphene oxide as a catalyst for the selective oxidation of glycerol

RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37112-37118 ◽  
Author(s):  
Gao-Yuan Yang ◽  
Shuai Shao ◽  
Yi-Hu Ke ◽  
Chun-Ling Liu ◽  
Hui-Fang Ren ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Graphene Oxide ◽  
Catalytic Activity ◽  
Selective Oxidation ◽  
High Catalytic Activity ◽  
Alloy Nanoparticles

Thermally expanded graphene oxide supported PtAu alloy nanoparticles showed high catalytic activity in the oxidation of glycerol in base-free aqueous solution.

In situ Synthesis of Reduced Graphene Oxide Supported CoMo Nanoparticles as Efficient Catalysts for Hydrogen Generation from NH3BH3

2018 ◽  
Vol 232 (3) ◽  
pp. 431-443 ◽  
Author(s):  
Xigang Du ◽  
Yonghua Duan ◽  
Jun Zhang ◽  
Gang Mi
Keyword(s):  
Aqueous Solution ◽  
Graphene Oxide ◽  
Catalytic Activity ◽  
Reduced Graphene Oxide ◽  
Hydrogen Generation ◽  
Sodium Molybdate ◽  
High Catalytic Activity ◽  
Ambient Conditions ◽  
Reduced Graphene

AbstractCoMo nanoparticles (NPs) supported on reduced graphene oxide (RGO) were synthesized by a one-stepin situco-reduction of an aqueous solution of cobalt(II) chloride, sodium molybdate dihydrate and graphene oxide (GO) using NaBH4as the sole reductant under ambient conditions. The powder XRD, FTIR, EDS and TEM were employed to characterize the structure, size and composition of the CoMo/RGO catalysts. The as-synthesized Co0.9Mo0.1/RGO catalysts exhibited high catalytic activity for the hydrolytic dehydrogenation of ammonia borane (AB) at room temperature. The as-synthesized Co0.9Mo0.1/RGO nanocatalysts exhibited much higher catalytic activity than Co/RGO, Mo/RGO and the RGO-free Co0.9Mo0.1counterpart. Moreover, kinetic studies indicate that the catalytic hydrolysis of AB by Co0.9Mo0.1/RGO has first order kinetics with respect to the the catalyst concentration, but zero order kinetics with respect to the substrate concentration. The Co0.9Mo0.1/RGO catalyst has a turnover frequency (TOF) of 15.8 mol H2·(mol·Co0.9Mo0.1/RGO)−1·min−1at 25°C. Furthermore, the Co0.9Mo0.1/RGO show good recyclability for hydrogen generation from an aqueous solution of AB, which enables the practical reuse of the catalysts. Hence, this general method can be easily extended to the facile preparation of other RGO-based metallic systems.

3D Porous Nb2C MXene/Reduced Graphene Oxide Aerogel Coupled with NiFe Alloy Nanoparticles for Wearable Zn–Air Batteries

2021 ◽  
Author(s):  
Hang Lei ◽  
Shangjing Yang ◽  
Runquan Lei ◽  
Qing Zhong ◽  
Qixiang Wan ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Reduced Graphene Oxide ◽  
Active Sites ◽  
Alloy Nanoparticles ◽  
Reduced Graphene ◽  
Reduced Graphene Oxide Aerogel ◽  
Graphene Oxide Aerogel ◽  
Catalytic Processes

Insufficient catalytic activity and self-restacking of 2D MXenes during catalytic processes would lead to limited number of active sites, sluggish ionic kinetics and poor durability, extremely restricting its application in...

Mussel-inspired construction of thermo-responsive double-hydrophilic diblock copolymers-decorated reduced graphene oxide as effective catalyst supports for highly dispersed superfine Pd nanoparticles

Nanoscale ◽  
2018 ◽  
Vol 10 (26) ◽  
pp. 12487-12496 ◽  
Author(s):  
Haichao Duan ◽  
Yu Yang ◽  
Jianhua Lü ◽  
Changli Lü
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Reduced Graphene Oxide ◽  
Diblock Copolymer ◽  
Diblock Copolymers ◽  
Pd Nanoparticles ◽  
Catalyst Supports ◽  
High Catalytic Activity ◽  
Reduced Graphene ◽  
Highly Dispersed

We report a facile, mussel-inspired construction of a thermo-responsive diblock copolymer-anchored rGO support for superfine PdNPs with high catalytic activity.

scholarly journals Correction: Facile preparation of reduced graphene oxide supported PtNi alloyed nanosnowflakes with high catalytic activity

RSC Advances ◽  
2015 ◽  
Vol 5 (57) ◽  
pp. 45641-45641
Author(s):  
Pei Song ◽  
Jiu-Ju Feng ◽  
Shu-Xian Zhong ◽  
Su-Su Huang ◽  
Jian-Rong Chen ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Reduced Graphene Oxide ◽  
High Catalytic Activity ◽  
Reduced Graphene ◽  
Facile Preparation

Correction for ‘Facile preparation of reduced graphene oxide supported PtNi alloyed nanosnowflakes with high catalytic activity’ by Pei Song et al., RSC Adv., 2015, 5, 35551–35557.

A facile construction of Au nanoparticles on a copolymer ligand brushes modified graphene oxide nanoplatform with excellent catalytic properties

RSC Advances ◽  
2016 ◽  
Vol 6 (69) ◽  
pp. 64937-64945 ◽  
Author(s):  
Yajiao Song ◽  
Jianhua Lü ◽  
Bingxin Liu ◽  
Changli Lü
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Au Nanoparticles ◽  
Catalytic Properties ◽  
High Catalytic Activity ◽  
Au Nps ◽  
Modified Graphene Oxide ◽  
Modified Graphene ◽  
Copolymer Brush

Au NPs were generated via in situ reduction on copolymer brush P(OEGMA-co-MQ) functionalized GO. MQ units in the brushes as capping agents could stabilize the Au NPs. The Au NPs–GO hybrid exhibited high catalytic activity for the reduction of 4-NP.

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