Cross dehydrogenative coupling (CDC) of aldehydes with N-hydroxyimides by visible light photoredox catalysis

RSC Advances ◽  
2015 ◽  
Vol 5 (56) ◽  
pp. 44928-44932 ◽  
Author(s):  
Milan Dinda ◽  
Chandan Bose ◽  
Tridev Ghosh ◽  
Soumitra Maity
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Dehydrogenative Coupling

A visible light mediated cross-dehydrogenative-coupling (CDC) reaction has been developed for the synthesis of N-hydroxyester derivatives from aldehydes and N-hydroxyimides.

ChemInform Abstract: Cross Dehydrogenative Coupling (CDC) of Aldehydes with N-Hydroxyimides by Visible Light Photoredox Catalysis.

ChemInform ◽  
2015 ◽  
Vol 46 (41) ◽  
pp. no-no
Author(s):  
Milan Dinda ◽  
Chandan Bose ◽  
Tridev Ghosh ◽  
Soumitra Maity
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Dehydrogenative Coupling

scholarly journals C(sp2)–H/O–H cross-dehydrogenative coupling of quinoxalin-2(1H)-ones with alcohols under visible-light photoredox catalysis

2020 ◽  
Vol 41 (8) ◽  
pp. 1168-1173 ◽  
Author(s):  
Long-Yong Xie ◽  
Yi-Shu Liu ◽  
Hong-Ru Ding ◽  
Shao-Feng Gong ◽  
Jia-Xi Tan ◽  
...  
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Dehydrogenative Coupling

Metal-Free C(sp2)–H/N–H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis

2018 ◽  
Vol 20 (22) ◽  
pp. 7125-7130 ◽  
Author(s):  
Wei Wei ◽  
Leilei Wang ◽  
Pengli Bao ◽  
Yun Shao ◽  
Huilan Yue ◽  
...  
Keyword(s):  
Visible Light ◽  
Aliphatic Amines ◽  
Photoredox Catalysis ◽  
Metal Free ◽  
Dehydrogenative Coupling

scholarly journals Enantioselective aerobic oxidative cross-dehydrogenative coupling of glycine derivatives with ketones and aldehydes via cooperative photoredox catalysis and organocatalysis

2020 ◽  
Vol 11 (18) ◽  
pp. 4741-4746 ◽  
Author(s):  
Xiaorong Yang ◽  
Zhixiang Xie ◽  
Ying Li ◽  
Yuan Zhang
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Dehydrogenative Coupling ◽  
Glycine Derivatives

A visible-light-induced enantioselective aerobic oxidative cross-dehydrogenative coupling between glycine derivatives and simple ketones or aldehydes is achieved.

scholarly journals Efficient merging of copper and photoredox catalysis for the asymmetric cross-dehydrogenative-coupling of alkynes and tetrahydroisoquinolines

2015 ◽  
Vol 13 (2) ◽  
pp. 447-451 ◽  
Author(s):  
Inna Perepichka ◽  
Soumen Kundu ◽  
Zoë Hearne ◽  
Chao-Jun Li
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Highly Efficient ◽  
Dehydrogenative Coupling ◽  
Catalytic Asymmetric

A highly efficient catalytic asymmetric alkynylation of prochiral CH2 groups in tetrahydroisoquinoline was developed using copper catalyzed cross-dehydrogenative-coupling of sp3 and sp C–H bonds with the assistance of a photocatalyst and visible light.

Regioselective C3-H Trifluoromethylation of 2H-Indazole Under Transition-Metal-Free Photoredox Catalysis

2019 ◽  
Author(s):  
Arumugavel Murugan ◽  
Venkata Nagarjuna Babu ◽  
Nagaraj Sabarinathan ◽  
Sharada Duddu. S
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Practical Approach ◽  
Hypervalent Iodine ◽  
Radical Mechanism ◽  
Photoredox Catalysis ◽  
Metal Free

Here we report a visible-light-promoted metal-free regioselective C3-H trifluoromehtylation reaction that proceeds via radical mechanism and which supported by control experiments. The combination of photoredox catalysis and hypervalent iodine reagent provides a practical approach for the present trifluoromethylation reaction and synthesis of a library of trifluoromethylated indazoles.

Enantioselective Radical Functionalization of Imines and Iminium Intermediates via Visible Light Photoredox Catalysis

Synthesis ◽  
2020 ◽  
Author(s):  
Jia-Jia Zhao ◽  
Hong-Hao Zhang ◽  
Shouyun Yu
Keyword(s):  
Visible Light ◽  
Asymmetric Synthesis ◽  
Carbonyl Compounds ◽  
Asymmetric Reduction ◽  
Chemical Transformations ◽  
Photoredox Catalysis ◽  
Radical Coupling ◽  
Mild Conditions ◽  
Iminium Ions ◽  
Radical Functionalization

Visible light photoredox catalysis has recently emerged as a powerful tool for the development of new and valuable chemical transformations under mild conditions. Visible-light promoted enantioselective radical transformations of imines and iminium intermediates provide new opportunities for the asymmetric synthesis of amines and asymmetric β-functionalization of unsaturated carbonyl compounds. In this review, the advance in the catalytic asymmetric radical functionalization of imines, as well as iminium intermediates, are summarized. 1 Introduction 2 The enantioselective radical functionalization of imines 2.1 Asymmetric reduction 2.2 Asymmetric cyclization 2.3 Asymmetric addition 2.4 Asymmetric radical coupling 3 The enantioselective radical functionalization of iminium ions 3.1 Asymmetric radical alkylation 3.2 Asymmetric radical acylation 4 Conclusion

Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis

2013 ◽  
Vol 15 (9) ◽  
pp. 2136-2139 ◽  
Author(s):  
Yusuke Yasu ◽  
Takashi Koike ◽  
Munetaka Akita
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Visible Light Driven
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