Facile synthesis of porous organic polymers bifunctionalized with azo and porphyrin groups

RSC Advances ◽  
2015 ◽  
Vol 5 (119) ◽  
pp. 98508-98513 ◽  
Author(s):  
Xiaowei Jiang ◽  
Yunfei Liu ◽  
Jun Liu ◽  
Yali Luo ◽  
Yinong Lyu

Azo and porphyrin bifunctionalized porous polymer networks (azo-PPors) with BET surface areas up to 750 m2 g−1 were synthesized via a catalyst-free direct coupling of tetra(4-nitrophenyl)porphyrin and aryl amine monomers.

2018 ◽  
Vol 1 (11) ◽  
pp. 6535-6540 ◽  
Author(s):  
Jiahuan Li ◽  
Zhonghua Cheng ◽  
Meifang Zhu ◽  
Arne Thomas ◽  
Yaozu Liao

2021 ◽  
Author(s):  
Zhi-Hao Zhang ◽  
Shan-Qing Peng ◽  
Shumeng Chi ◽  
Hanyuan Chen ◽  
Lei Fan ◽  
...  

Porous organic polymers (POPs) represented a class of promising materials for delivering environmental and energy issues worldwide. However, the nature of amorphous makes their structure characterization in the solid state...


2015 ◽  
Vol 3 (48) ◽  
pp. 24422-24427 ◽  
Author(s):  
Sophie Kuecken ◽  
Johannes Schmidt ◽  
Linjie Zhi ◽  
Arne Thomas

Covalent triazine frameworks (CTFs) are prepared from amorphous, non-porous polymer networks using a facile and scalable procedure.


2018 ◽  
Vol 9 (36) ◽  
pp. 4585-4595 ◽  
Author(s):  
Jordy Guadalupe ◽  
Ana M. Ray ◽  
Eva M. Maya ◽  
Berta Gómez-Lor ◽  
Marta Iglesias

New, robust, insoluble porous organic polymers based on the semiconducting platform of hexamethyltruxene with high Brunauer–Emmett–Teller specific surface areas and interesting catalytic activity are presented.


Polymer ◽  
2010 ◽  
Vol 51 (26) ◽  
pp. 6193-6202 ◽  
Author(s):  
Guangwen Yang ◽  
Heyou Han ◽  
Chunyan Du ◽  
Zhihui Luo ◽  
Yanjun Wang

2021 ◽  
Author(s):  
Mohamed Gamal Mohamed ◽  
Ahmed F. M. EL-Mahdy ◽  
Mohammed G. Kotp ◽  
Shiao-Wei Kuo

Porous organic polymers (POPs) are organic macromolecules that are considered emerging materials because of their high specific surface areas, tunable porosities, low densities, high chemical and thermal stabilities, variable compositions,...


Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2426 ◽  
Author(s):  
Mohamed Gamal Mohamed ◽  
Ahmed. F. M. EL-Mahdy ◽  
Tso-Shiuan Meng ◽  
Maha Mohamed Samy ◽  
Shiao-Wei Kuo

We successfully prepared two different classes of hypercrosslinked porous organic polymers (HPPs)—the tetraphenylethene (TPE) and (4-(5,6-Diphenyl-1H-Benzimidazol-2-yl)-triphenylamine (DPT) HPPs—through the Friedel−Crafts polymerization of tetraphenylethene and 4-(5,6-diphenyl-1H-benzimidazol-2-yl)-triphenylamine, respectively, with 1,4-bis(chloromethyl)benzene (Ph-2Cl) in the presence of anhydrous FeCl3 as a catalyst. Our porous materials exhibited high BET surface areas (up to 1000 m2 g−1) and good thermal stabilities. According to electrochemical and dyes adsorption applications, the as-prepared DPT-HPP exhibited a high specific capacitance of 110 F g−1 at a current density of 0.5 A g−1, with an excellent cycling stability of over 2000 times at 10 A g−1. In addition, DPT-HPP showed a high adsorption capacity up to 256.40 mg g−1 for the removal of RhB dye from water.


2021 ◽  
Vol 258 ◽  
pp. 118049
Author(s):  
Wei Bai ◽  
Yukang Fan ◽  
Fei Wang ◽  
Peng Mu ◽  
Hanxue Sun ◽  
...  

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