Thermodynamic stability and transport properties of tavorite LiFeSO4F as a cathode material for lithium-ion batteries

2015 ◽  
Vol 3 (39) ◽  
pp. 19728-19737 ◽  
Author(s):  
Ying Xie ◽  
Hai-Tao Yu ◽  
Ting-Feng Yi ◽  
Qi Wang ◽  
Qing-Shan Song ◽  
...  

LiFeSO4F and FeSO4F exhibit high thermodynamic stability, excellent ionic conductance and poor electronic conductivities.

2012 ◽  
Vol 1440 ◽  
Author(s):  
Jiajia Tan ◽  
Ashutosh Tiwari

ABSTRACTLi2FeP2O7 is a newly developed polyanionic cathode material for high performance lithium ion batteries. It is considered very attractive due to its large specific capacity, good thermal and chemical stability, and environmental benignity. However, the application of Li2FeP2O7 is limited by its low ionic and electronic conductivities. To overcome the above problem, a solution-based technique was successfully developed to synthesize Li2FeP2O7 powders with very fine and uniform particle size (< 1 μm), achieving much faster kinetics. The obtained Li2FeP2O7 powders were tested in lithium ion batteries by measurements of cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge/discharge cycling. We found that the modified Li2FeP2O7 cathode could maintain a relatively high capacity even at fast discharge rates.


2021 ◽  
Vol 23 (10) ◽  
pp. 5992-5998
Author(s):  
Daniel Uxa ◽  
Helen J. Holmes ◽  
Kevin Meyer ◽  
Lars Dörrer ◽  
Harald Schmidt

Lithium tracer diffusivities in LiNi0.33Mn0.33Co0.33O2 cathode material for lithium-ion batteries follows the Arrhenius law with an activation energy of 0.85 eV.


2021 ◽  
Vol 421 ◽  
pp. 129964
Author(s):  
Guangchang Yang ◽  
Kai Pan ◽  
Feiyan Lai ◽  
Zhongmin Wang ◽  
Youqi Chu ◽  
...  

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