scholarly journals Synthesis of highly electrochemically active Li2S nanoparticles for lithium–sulfur-batteries

2015 ◽  
Vol 3 (31) ◽  
pp. 16307-16312 ◽  
Author(s):  
M. Kohl ◽  
J. Brückner ◽  
I. Bauer ◽  
H. Althues ◽  
S. Kaskel

Carbothermal reduction of lithium sulfate below its melting point was used to produce sub-micron sized lithium sulfide particles which retain the morphology of the source particle and achieve high discharge capacities up to 1360 mA h gsulfur−1.

Nanoscale ◽  
2015 ◽  
Vol 7 (34) ◽  
pp. 14385-14392 ◽  
Author(s):  
Zhe Li ◽  
Shiguo Zhang ◽  
Ce Zhang ◽  
Kazuhide Ueno ◽  
Tomohiro Yasuda ◽  
...  

Lithium sulfide/graphene composite as high capacity cathode material is facilely obtained by one-pot pyrolysis of graphene nanoplatelet aggregates and low-cost lithium sulfate.


MRS Advances ◽  
2019 ◽  
Vol 4 (49) ◽  
pp. 2627-2634 ◽  
Author(s):  
Erika Nagai ◽  
Timothy S. Arthur ◽  
Patrick Bonnick ◽  
Koji Suto ◽  
John Muldoon

AbstractThe electrochemical discharge mechanism is reported for all-solid lithium sulfur batteries. Upon milling with carbon fibers, the solid electrolyte used within the cathode composite becomes electrochemically active. Analysis with Raman spectroscopy and XPS revealed the importance of bridging S-S bond formation and breaking in lithium polysulfidophosphates during electrochemical lithiation of the active solid electrolyte. Remarkably, when sulfur is introduced as an active material in the cathode composite, lithium polysulfides are formed as an intermediate product before full lithiation into lithium sulfide. The synthesis of materials based on bridging S-S bonds is an important avenue to the design of new cathodes for all-solid batteries.


Author(s):  
Yun-Wei Song ◽  
Jin-Lei Qin ◽  
Chang-Xin Zhao ◽  
Meng Zhao ◽  
Li-Peng Hou ◽  
...  

2018 ◽  
Vol 6 (18) ◽  
pp. 8655-8661 ◽  
Author(s):  
Chao Wu ◽  
Chunxian Guo ◽  
JingGao Wu ◽  
Wei Ai ◽  
Ting Yu ◽  
...  

A stable lithium sulfide membrane is constructedin situto wrap the mixed sulfur/C material surface of a lithium–sulfur battery (LSB) by delicately tuning the galvanostatic discharge current.


ACS Nano ◽  
2020 ◽  
Vol 14 (8) ◽  
pp. 10115-10126 ◽  
Author(s):  
Feng Ma ◽  
Yangyang Wan ◽  
Xiaoming Wang ◽  
Xinchao Wang ◽  
Jiashun Liang ◽  
...  

2017 ◽  
Vol 7 (20) ◽  
pp. 1701122 ◽  
Author(s):  
Michael J. Klein ◽  
Andrei Dolocan ◽  
Chenxi Zu ◽  
Arumugam Manthiram

2015 ◽  
Vol 1120-1121 ◽  
pp. 493-497
Author(s):  
Guang Hui Yuan ◽  
Jin Tao Bai

Using Orange Peels as Raw Material, a Stacking Structured Carbon Material has been Synthesized through Carbonizing and Activating Process. an Orange Peel Carbon/sulfur (OPC/S) Composite as a Cathode for Rechargeable Lithium/sulfur (Li/S) Batteries is Designed by Loading Sulfur into the Orange Peel Carbon (OPC) via Simple Impregnation and Heat Treatments. the OPC/S Composite Exhibits a High Discharge Capacity of 1100 mAh g−1 at 0.1 C, which is 23% Higher than that of Pristine Sulfur. Moreover, OPC/S Shows much Better Rate Capability and Excellent Cyclability. this Enhanced Electrochemical Performance could Be Attributed to the Thin Sheets and Irregular Wrinkled Surface of the OPC, which Act as a Conductor to Provide a Highly Conductivity and Short Li+ Diffusion Distance, as well as Absorbs Polysulfides.


Small Methods ◽  
2020 ◽  
Vol 4 (6) ◽  
pp. 2070020
Author(s):  
Meng Zhao ◽  
Hong‐Jie Peng ◽  
Jun‐Yu Wei ◽  
Jia‐Qi Huang ◽  
Bo‐Quan Li ◽  
...  

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