Ruthenium complexes bearing an unsymmetrical pincer ligand with a 2-hydroxypyridylmethylene fragment: active catalysts for transfer hydrogenation of ketones

2016 ◽  
Vol 45 (11) ◽  
pp. 4828-4834 ◽  
Author(s):  
Jing Shi ◽  
Bowen Hu ◽  
Dawei Gong ◽  
Shu Shang ◽  
Guangfeng Hou ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Pincer Ligand ◽  
Hydrogenation Activity ◽  
Catalytic Transfer ◽  
Metal Ligand

The synthesis, reactivity and catalytic transfer hydrogenation activity of three metal–ligand cooperative ruthenium(ii) complexes (3–5) with a 2-hydroxypyridylmethylene fragment are reported.

Novel ruthenium complexes bearing bipyridine-based and N-heterocyclic carbene-supported pyridine (NCN) ligands: the influence of ligands for catalytic transfer hydrogenation of ketones

2021 ◽  
Author(s):  
Akkharadet Piyasaengthong ◽  
Luke J Williams ◽  
Dmitry S Yufit ◽  
James William Walton
Keyword(s):  
Ruthenium Complexes ◽  
Metal Catalysts ◽  
Transfer Hydrogenation ◽  
Secondary Alcohols ◽  
Catalytic Transfer Hydrogenation ◽  
Homogeneous Catalysts ◽  
Catalytic Transfer

Transfer hydrogenation (TH) is a powerful synthetic tool in the production of secondary alcohols from ketones by using a non-H2 hydrogen source along with metal catalysts. Among homogeneous catalysts, Ru(II)...

scholarly journals Carbohydrate-functionalized N-heterocyclic carbene Ru(ii) complexes: synthesis, characterization and catalytic transfer hydrogenation activity

2019 ◽  
Vol 48 (31) ◽  
pp. 11838-11847 ◽  
Author(s):  
Joseph P. Byrne ◽  
Pauline Musembi ◽  
Martin Albrecht
Keyword(s):  
Metal Complex ◽  
Hybrid System ◽  
Transfer Hydrogenation ◽  
Hydrogenation Catalyst ◽  
Catalytic Transfer Hydrogenation ◽  
Hydrogenation Activity ◽  
Catalytic Transfer

Triazolylidene NHCs decorated with a carbohydrate wingtip group were complexed to a ruthenium(ii) center. Deprotection of the carbohydrate in the metal complex affords a carbohydrate–NHC hybrid system for use as a transfer hydrogenation catalyst.

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