An efficient method for regioselective ring opening of epoxides by amines under microwave irradiation using Bi(NO3)3·5H2O as a catalyst

2017 ◽  
Vol 41 (7) ◽  
pp. 2668-2671 ◽  
Author(s):  
Shobha Bansal ◽  
Yogendra Kumar ◽  
Parveen Pippal ◽  
Dipak K. Das ◽  
Panchanan Pramanik ◽  
...  

Bi(NO3)3·5H2O a highly efficient environmentally benign catalyst, is used for the nucleophilic ring opening of epoxides with aromatic, aliphatic and heteroaromatic amines under solvent free microwave conditions to afford the corresponding β-amino alcohols in good to excellent yields with high regioselectivity.

2008 ◽  
Vol 2008 (4) ◽  
pp. 220-221 ◽  
Author(s):  
Dadkhoda Ghazanfari ◽  
Mohammed M. Hashemi ◽  
Mohammad Mehdi Mottaghi ◽  
Mohammad Mehdi Foroughi

2007 ◽  
Vol 264 (1-2) ◽  
pp. 162-169 ◽  
Author(s):  
Rukhsana Ilyas Kureshy ◽  
Surendra Singh ◽  
Noor-ul Hasan Khan ◽  
Sayed Hasan Razi Abdi ◽  
Eringathodi Suresh ◽  
...  

2020 ◽  
Vol 56 (15) ◽  
pp. 2256-2259
Author(s):  
Dong Li ◽  
Jing Wang ◽  
Shibo Yu ◽  
Silei Ye ◽  
Wenjie Zou ◽  
...  

We herein report a metal- and solvent-free acetic acid-mediated ring-opening reaction of epoxides with amines.


2008 ◽  
Vol 86 (1) ◽  
pp. 65-71 ◽  
Author(s):  
Mona Hosseini-Sarvari

MgO catalyzed efficiently the ring opening of epoxides with a range of aromatic and aliphatic amines to produce β-substituted alcohols in high yields under solvent-free conditions. Exclusive trans stereoselectivity is observed for cyclic epoxide.Key words: MgO, β-amino alcohols, solvent-free, epoxide, amine.


2016 ◽  
Vol 524 ◽  
pp. 50-55 ◽  
Author(s):  
Thangaraj Baskaran ◽  
Akanksha Joshi ◽  
Gunda Kamalakar ◽  
Ayyamperumal Sakthivel

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