Hierarchical superstructures of norbornene-based polymers depending on dendronized side-chains

2016 ◽  
Vol 7 (33) ◽  
pp. 5304-5311 ◽  
Author(s):  
Dae-Yoon Kim ◽  
Dong-Gue Kang ◽  
Suyong Shin ◽  
Tae-Lim Choi ◽  
Kwang-Un Jeong

For understanding the self-assembly behaviours of norbornene-based main-chain polymers depending on side-chain pendants, a series of polynorbornenes containing the programmed dendrons is newly designed and successfully synthesized via ring opening metathesis polymerization.

2012 ◽  
Vol 45 (7) ◽  
pp. 2963-2971 ◽  
Author(s):  
Wen-Yong Lai ◽  
Michael N. Balfour ◽  
Jack W. Levell ◽  
Ashu K. Bansal ◽  
Paul L. Burn ◽  
...  

2018 ◽  
Vol 51 (21) ◽  
pp. 8940-8955 ◽  
Author(s):  
Christiana Nikovia ◽  
Lazaros Theodoridis ◽  
Stelios Alexandris ◽  
Panayiotis Bilalis ◽  
Nikos Hadjichristidis ◽  
...  

2021 ◽  
Author(s):  
Taichi Sotani ◽  
Toshiko Mizokuro ◽  
Tatsuo Yajima ◽  
Hiromitsu Sogawa ◽  
Fumio Sanda

Ring-opening metathesis polymerization (ROMP) of norbornene derivatives is useful for preparing thermally stable and transparent polymeric materials with good moldability. This study deals with ROMP of norbornene monomer 1 bearing...


Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 298 ◽  
Author(s):  
Ioannis Choinopoulos

In this review, molecular brushes and other macromolecular architectures bearing a bottlebrush segment where the main chain is synthesized by ring opening metathesis polymerization (ROMP) mediated by Mo or Ru metal complexes are considered. A brief review of metathesis and ROMP is presented in order to understand the problems and the solutions provided through the years. The synthetic strategies towards bottlebrush copolymers are demonstrated and each one discussed separately. The initiators/catalysts for the synthesis of the backbone with ROMP are discussed. Syntheses of molecular brushes are presented. The most interesting properties of the bottlebrushes are detailed. Finally, the applications studied by different groups are presented.


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