scholarly journals Highly efficient metal organic framework (MOF)-based copper catalysts for the base-free aerobic oxidation of various alcohols

RSC Advances ◽  
2017 ◽  
Vol 7 (29) ◽  
pp. 17806-17812 ◽  
Author(s):  
Abu Taher ◽  
Dong Wook Kim ◽  
Ik-Mo Lee

Copper containing metal organic frameworks (MOFs) are found to be highly efficient heterogeneous catalysts for alcohol oxidation.

2020 ◽  
Vol 24 (16) ◽  
pp. 1876-1891
Author(s):  
Qiuyun Zhang ◽  
Yutao Zhang ◽  
Jingsong Cheng ◽  
Hu Li ◽  
Peihua Ma

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.


2020 ◽  
Vol 8 (39) ◽  
pp. 20386-20392
Author(s):  
Mengke Cai ◽  
Yawei Zhang ◽  
Yiyue Zhao ◽  
Qinglin Liu ◽  
Yinle Li ◽  
...  

2D metal–organic frameworks (MOFs) could promote biomass valorization, and electrooxidation of 5-(hydroxymethyl)furfural (HMF) into 2,5-furandicarboxylic acid (FDCA) with a highly efficient electrocatalytic performance.


2015 ◽  
Vol 51 (60) ◽  
pp. 12020-12023 ◽  
Author(s):  
Yong Liu ◽  
Xingtao Xu ◽  
Miao Wang ◽  
Ting Lu ◽  
Zhuo Sun ◽  
...  

Porous carbon polyhedra were synthesized through direct carbonization of metal–organic frameworks and used as an electrode material for capacitive deionization.


2019 ◽  
Vol 9 (6) ◽  
pp. 1511-1517 ◽  
Author(s):  
Yusuke Isaka ◽  
Yoshifumi Kondo ◽  
Yasutaka Kuwahara ◽  
Kohsuke Mori ◽  
Hiromi Yamashita

Encapsulation of [Ru(bpy)3]2+ in the cavity of a metal–organic framework was found to enhance its activity in the photocatalytic aerobic oxidation of benzyl alcohol.


2016 ◽  
Vol 4 (15) ◽  
pp. 5467-5473 ◽  
Author(s):  
Xingtao Xu ◽  
Miao Wang ◽  
Yong Liu ◽  
Ting Lu ◽  
Likun Pan

Novel carbon nanotube-inserted porous carbon polyhedra synthesized from metal–organic frameworks were used for capacitive deionization with a superior electrosorption capacity.


Author(s):  
Jun Jin ◽  
You-fang Zhang ◽  
Huanwen Wang ◽  
Yansheng Gong ◽  
Rui Wang ◽  
...  

Recently, metal–organic frameworks (MOFs) have been used to synthesize electrode materials such as porous carbon, metal oxides, and metal chalcogenides or directly utilized as electrodes. However, pristine MOF electrodes suffer...


2020 ◽  
Vol 8 (4) ◽  
pp. 2140-2146 ◽  
Author(s):  
Qi Hu ◽  
Xiaowan Huang ◽  
Ziyu Wang ◽  
Guomin Li ◽  
Zhen Han ◽  
...  

A controllable calcination route was developed for the crafting ultrafine NiO nanoparticles within ultrathin Ni-based metal–organic frameworks (Ni-MOFs), which are highly efficient for oxygen evolution reaction.


2019 ◽  
Vol 21 (13) ◽  
pp. 3629-3636 ◽  
Author(s):  
Jingwen Chen ◽  
Minda Chen ◽  
Biying Zhang ◽  
Renfeng Nie ◽  
Ao Huang ◽  
...  

Manganese-based CPF-5 as a highly efficient catalyst for the selective aerobic oxidation of cyclohexene to cyclohexenone under mild conditions.


2016 ◽  
Vol 6 (5) ◽  
pp. 1515-1522 ◽  
Author(s):  
Carlos M. Granadeiro ◽  
Lucie S. Nogueira ◽  
Diana Julião ◽  
Fátima Mirante ◽  
Duarte Ananias ◽  
...  

An aluminum 2-aminoterephthalate based metal–organic framework material was used to prepare highly efficient heterogeneous catalysts in desulfurization processes.


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