Palladium-catalyzed difluoromethylthiolation of heteroaryl bromides, iodides, triflates and aryl iodides

An enantioselective Pd-catalyzed silicon–carbon bond-forming silylation reaction of aryl iodides with hydrosilanes for the synthesis of silicon-stereogenic silanes has been developed with good enantioselectivity under mild conditions.

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Streamlined construction of peptide macrocycles via palladium-catalyzed intramolecular S-arylation in solution and on DNA

Chemical Science ◽

10.1039/d1sc00789k ◽

2021 ◽

Vol 12 (16) ◽

pp. 5804-5810

Author(s):

Peng Yang ◽

Xuan Wang ◽

Bo Li ◽

Yixuan Yang ◽

Jinfeng Yue ◽

...

Keyword(s):

Mild Conditions ◽

Highly Efficient ◽

Aryl Iodides ◽

Palladium Catalyzed

A highly efficient and versatile method for construction of peptide macrocycles via palladium-catalyzed intramolecular S-arylation of alkyl and aryl thiols with aryl iodides under mild conditions is developed.

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Synthesis of S-aryl thioesters via palladium-catalyzed thiocarbonylation of aryl iodides and aryl sulfonyl hydrazides

Organic Chemistry Frontiers ◽

10.1039/d0qo00748j ◽

2020 ◽

Vol 7 (19) ◽

pp. 2938-2943

Author(s):

Yeojin Kim ◽

Kwang Ho Song ◽

Sunwoo Lee

Keyword(s):

Aryl Iodide ◽

Aryl Iodides ◽

Palladium Catalyzed

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.

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Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

Organic Chemistry Frontiers ◽

10.1039/d0qo00158a ◽

2020 ◽

Vol 7 (6) ◽

pp. 885-889 ◽

Cited By ~ 2

Author(s):

Xinxin Qi ◽

Zhi-Peng Bao ◽

Xiao-Feng Wu

Keyword(s):

Sulfonyl Chlorides ◽

Aryl Iodides ◽

Palladium Catalyzed ◽

Convenient Access

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides to thioesters has been studied.

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Palladium-Catalyzed Asymmetric Annulation Between Aryl Iodides and Racemic Epoxides Using a Chiral Norbornene Cocatalyst

10.26434/chemrxiv.6635312 ◽

2018 ◽

Author(s):

Guangbin Dong ◽

Renhe Li

Keyword(s):

Isopropyl Ester ◽

Synthetic Route ◽

Initial Development ◽

Aryl Iodides ◽

Palladium Catalyzed

Herein, we describe our initial development of an asymmetric Pd-catalyzed annulation between aryl iodides and racemic epoxides for synthesis of 2,3-dihydrobenzofurans using a chiral norbornene cocatalyst. A series of enantiopure ester-, amide- and imide-substituted norbornenes have been prepared with a reliable synthetic route. Promising enantioselectivity (42-45% ee) has been observed using the isopropyl ester-substituted norbornene (N1*) and the amide-substituted norbornene (N7*).

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Palladium-Catalyzed One-Pot Three- or Four-Component Coupling of Aryl Iodides, Alkynes, and Amines through CN Bond Cleavage: Efficient Synthesis of Indole Derivatives

Chemistry - A European Journal ◽

10.1002/chem.201304215 ◽

2014 ◽

Vol 20 (9) ◽

pp. 2605-2612 ◽

Cited By ~ 37

Author(s):

Wei Hao ◽

Weizhi Geng ◽

Wen-Xiong Zhang ◽

Zhenfeng Xi

Keyword(s):

Bond Cleavage ◽

Indole Derivatives ◽

Efficient Synthesis ◽

One Pot ◽

Aryl Iodides ◽

Palladium Catalyzed

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Nickel-Catalyzed Asymmetric Reductive Cross-Coupling of α-Chloroesters with (Hetero)Aryl Iodides

Chemical Science ◽

10.1039/d1sc00822f ◽

2021 ◽

Author(s):

Travis DeLano ◽

Sara Dibrell ◽

Caitlin R. Lacker ◽

Adam Pancoast ◽

Kelsey Poremba ◽

...

Keyword(s):

Cross Coupling ◽

Mild Conditions ◽

Aryl Iodides ◽

Reaction Proceeds

An asymmetric reductive cross-coupling of α-chloroesters and (hetero)aryl iodides is reported. This nickel-catalyzed reaction proceeds with a chiral BiOX ligand under mild conditions, affording α-arylesters in good yields and enantioselectivities....

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