Synthesis of novel nonlinear optical chromophores: achieving enhanced electro-optic activity and thermal stability by introducing rigid steric hindrance groups into the julolidine donor

2017 ◽  
Vol 5 (7) ◽  
pp. 1675-1684 ◽  
Author(s):  
Hua Zhang ◽  
Hongyan Xiao ◽  
Fenggang Liu ◽  
Fuyang Huo ◽  
Yanling He ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Steric Hindrance ◽  
Nonlinear Optical ◽  
Electro Optic ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

A series of chromophores based on julolidine donors modified by four different rigid steric hindrance groups with the same thiophene bridges and strong tricyanovinyldihydrofuran acceptors were synthesised.

Synthesis of nonlinear optical chromophores with isophorone-derived bridges for enhanced thermal stability and electro-optic activity

2020 ◽  
Vol 8 (27) ◽  
pp. 9226-9235 ◽  
Author(s):  
Fenggang Liu ◽  
Songmin Mo ◽  
Zhaofen Zhai ◽  
Meishan Peng ◽  
Shuangke Wu ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Nonlinear Optical ◽  
Electro Optic ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

In this work, we developed a series of nonlinear optical chromophores J1–J4 with the same julolidinyl-based donor and tricyanovinyldihydrofuran acceptor with different modified isophorone-derived bridges.

Enhanced thermal stability and electro-optic activity from fluorene-based nonlinear optical chromophores

2020 ◽  
Vol 183 ◽  
pp. 108751
Author(s):  
Fenggang Liu ◽  
Canwen Yu ◽  
Gangzhi Qin ◽  
Meishan Peng ◽  
Ziwei Wang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Nonlinear Optical ◽  
Electro Optic ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

Nonlinear optical chromophores containing a novel pyrrole-based bridge: optimization of electro-optic activity and thermal stability by modifying the bridge

2014 ◽  
Vol 2 (37) ◽  
pp. 7785-7795 ◽  
Author(s):  
Fenggang Liu ◽  
Haoran Wang ◽  
Yuhui Yang ◽  
Huajun Xu ◽  
Maolin Zhang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Nonlinear Optical ◽  
Electro Optic ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

New chromophores containing a novel pyrrole-based bridge were synthesized and the hyperpolarizability can be effectively translated into large electro-optic coefficients in poled polymers.

Large Electro-optic Activity and Enhanced Thermal Stability from Diarylaminophenyl-Containing High-β Nonlinear Optical Chromophores

2007 ◽  
Vol 19 (5) ◽  
pp. 1154-1163 ◽  
Author(s):  
Yen-Ju Cheng ◽  
Jingdong Luo ◽  
Steven Hau ◽  
Denise H. Bale ◽  
Tae-Dong Kim ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Nonlinear Optical ◽  
Electro Optic ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

Auxiliary donor for tetrahydroquinoline-containing nonlinear optical chromophores: enhanced electro-optical activity and thermal stability

2015 ◽  
Vol 3 (36) ◽  
pp. 9283-9291 ◽  
Author(s):  
Fenggang Liu ◽  
Maolin Zhang ◽  
Hongyan Xiao ◽  
Yuhui Yang ◽  
Haoran Wang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Optical Activity ◽  
Nonlinear Optical ◽  
Electro Optic ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

New chromophores L1 and L2 containing a novel tetrahydroquinoline-based donor were synthesized, resulting in enhanced electro-optic activity.

The synthesis of second-order nonlinear optical chromophores with conjugated steric hindrance for electro-optics at 850 nm

2020 ◽  
Vol 8 (16) ◽  
pp. 5494-5500 ◽  
Author(s):  
Jieyun Wu ◽  
Wen Wang ◽  
Kaixin Chen ◽  
Jingdong Luo
Keyword(s):  
Steric Hindrance ◽  
Nonlinear Optical ◽  
Second Order ◽  
Electro Optic ◽  
Nonlinear Optical Chromophore ◽  
Nonlinear Optical Chromophores ◽  
Shortwave Infrared ◽  
Optical Chromophores ◽  
Infrared Window

We show the strategy of introducing a suitable conjugated site-isolator on the bridge of a nonlinear optical chromophore to significantly improve the electro-optic activity at the shortwave infrared window (850 nm) for electro-optic modulation.

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