Effect of the Two-Dimensional Magnetostrictive Fillers of CoFe2O4-Intercalated Graphene Oxide Sheets in 3-2 Type Poly(vinylidene fluoride)-Based Magnetoelectric Films

In the last decade, magnetoelectric (ME) polymer films have been developed by including zero-dimensional or one-dimensional magnetostrictive fillers in a piezoelectric polymer matrix. Existing reports on ME polymer films reveal that the shape of the magnetostrictive fillers is a critical determinant of the polymeric phase conformation, strain transfer between the piezoelectric and magnetostrictive phases, and dipole alignment in the films. In this study, to investigate the effect of two-dimensional (2D) magnetostrictive fillers on piezoelectric, magnetic, and magnetoelectric responses, 3-2 type ME films were prepared using CoFe2O4-intercalated graphene oxide (CFO-i-GO) fillers and poly(vinylidene fluoride) (PVDF) polymers. The 2D fillers of CFO-i-GO were hydrothermally synthesized by CFO intercalation into the interlayers of GO sheets with different lateral sizes, which were controlled by ultrasonication treatment. It was found that the large-lateral-size GO (LGO), medium-lateral-size GO (MGO), and small-lateral-size GO (SGO) fillers in the PVDF-based ME films exhibited a lateral size effect on CFO intercalation, polymeric phase conformation, dipole alignment, and magnetoelectric responses. A maximum ME coefficient (αME) of 3.0 mV/cm∙Oe was achieved with a strong linearity (r2) of 0.9992 at an off-resonance frequency (f) of 1 kHz and applied direct current (dc) magnetic field (Hdc) of ± 1000 Oe. The 3-2 type polymer-based ME films with reliable ME responses have potential for use in high-feasibility ME devices for biomedical sensing applications.

Magnetic Helicity and the Geodynamo

We present theoretical and computational results in magnetohydrodynamic turbulence that we feel are essential to understanding the geodynamo. These results are based on a mathematical model that focuses on magnetohydrodynamic (MHD) turbulence, but ignores compressibility and thermal effects, as well as imposing model-dependent boundary conditions. A principal finding is that when a turbulent magnetofluid is in quasi-equilibrium, the magnetic energy in the internal dipole component is equal to the magnetic helicity multiplied by the dipole wavenumber. In the case of the Earth, measurement of the exterior magnetic field gives us, through boundary conditions, the internal poloidal magnetic field. The connection between magnetic helicity and dipole field in the liquid core then gives us the toroidal part of the internal dipole field and a model value of 3 mT for the average core dipole magnetic field. Here, we present the theoretical analysis and numerical simulations that lead to these conclusions. We also test an earlier assertion that differential oblateness may be related to dipole alignment, and while there is an effect, rotation appears to be far more important. In addition, the relationship between dipole quasi-stationarity, broken ergodicity and broken symmetry is clarified. Lastly, we discuss how inertial waves in a rotating magnetofluid can affect dipole alignment.

Unprecedented dipole alignment in α-phase nylon-11 nanowires for high-performance energy-harvesting applications

Dipole alignment in ferroelectric polymers is routinely exploited for applications in charge-based applications. Here, we present the first experimental realization of ideally ordered dipole alignment in α-phase nylon-11 nanowires. This is an unprecedented discovery as dipole alignment is typically only ever achieved in ferroelectric polymers using an applied electric field, whereas here, we achieve dipole alignment in as-fabricated nanowires of ‘non-ferroelectric’ α-phase nylon-11, an overlooked polymorph of nylon proposed 30 years ago but never practically realized. We show that the strong hydrogen bonding in α-phase nylon-11 serves to enhance the molecular ordering, resulting in exceptional intensity and thermal stability of surface potential. This discovery has profound implications for the field of triboelectric energy harvesting, as the presence of an enhanced surface potential leads to higher mechanical energy harvesting performance. Our approach therefore paves the way towards achieving robust, high-performance mechanical energy harvesters based on this unusual ordered phase of nylon-11.

High-efficiency organic light-emitting diodes with exciplex hosts

Exciplex forming co-hosts have been applied to fabricate high-efficiency organic light-emitting diodes (OLEDs) due to the merits of bipolarity, 100% exciton harvesting, preferred dipole alignment, and sensitizing effects.