Crystalline magnesium chloride–electron donor complexes: new support materials for Ziegler–Natta catalysts

2017 ◽  
Vol 46 (13) ◽  
pp. 4452-4460 ◽  
Author(s):  
V. H. Nissinen ◽  
I. O. Koshevoy ◽  
T. T. Pakkanen
Keyword(s):  
Crystal Structure ◽  
Structure Formation ◽  
Magnesium Chloride ◽  
Donor Ligands ◽  
Nitrogen Donor Ligands ◽  
Support Materials ◽  
Polymerization Catalyst ◽  
Nitrogen Donor ◽  
Crystal Structure Formation ◽  
Ziegler Natta Catalysts

Chelating oxygen and nitrogen donor ligands (1,2-dimethoxyethane, 1,3-dimethoxypropane, and N,N′-diethylethylenediamine) are found to dictate the crystal structure formation of MgCl2, the important support component of a polymerization catalyst.

Synthesis, crystal structure and magnetic properties of the complex [ReCl3(tppz)]·MeCN

RSC Advances ◽  
2015 ◽  
Vol 5 (123) ◽  
pp. 101616-101622 ◽  
Author(s):  
J. Palion-Gazda ◽  
I. Gryca ◽  
B. Machura ◽  
Francesc Lloret ◽  
Miguel Julve
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Variable Temperature ◽  
Donor Ligands ◽  
Magnetic Data ◽  
Nitrogen Donor Ligands ◽  
X Ray ◽  
Nitrogen Donor

The paper reports the synthesis, X-ray structure and a deep analysis of the variable-temperature magnetic data of the new complex [ReCl3(tppz)]·MeCN being a very scarce example of mononuclear Re(iii) complexes incorporating nitrogen donor ligands.

scholarly journals Crystal structure of K[PtCl3(caffeine)] and its interactions with important nitrogen-donor ligands

2016 ◽  
Vol 69 (5) ◽  
pp. 735-747 ◽  
Author(s):  
Snežana Jovanović ◽  
Ralph Puchta ◽  
Olivera Klisurić ◽  
Živadin D. Bugarčić
Keyword(s):  
Crystal Structure ◽  
Donor Ligands ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor
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