Synthesis of new platinum(II) compounds with several bidentate and tridentate nitrogen-donor ligands. Structural analyses by 1H, 13C{1H} and 195Pt{1H} NMR spectroscopy and X-ray crystal structure

The paper reports the synthesis, X-ray structure and a deep analysis of the variable-temperature magnetic data of the new complex [ReCl3(tppz)]·MeCN being a very scarce example of mononuclear Re(iii) complexes incorporating nitrogen donor ligands.

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Synthesis of new palladium(II) complexes containing tetradentate-nitrogen donor ligands: Combined structural studies by NMR spectroscopy and X-ray crystallography

Inorganica Chimica Acta ◽

10.1016/j.ica.2007.11.011 ◽

2008 ◽

Vol 361 (9-10) ◽

pp. 2648-2658 ◽

Cited By ~ 12

Author(s):

Mònica Espinal ◽

Josefina Pons ◽

Jordi García-Antón ◽

Xavier Solans ◽

Mercè Font-Bardia ◽

...

Keyword(s):

Nmr Spectroscopy ◽

Donor Ligands ◽

Structural Studies ◽

Nitrogen Donor Ligands ◽

X Ray ◽

X Ray Crystallography ◽

Nitrogen Donor

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Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine

Baghdad Science Journal ◽

10.21123/bsj.2020.17.1(suppl.).0272 ◽

2020 ◽

Vol 17 (1(Suppl.)) ◽

pp. 0272

Author(s):

Ahmed Shukkur

Keyword(s):

Molecular Structure ◽

Crystal Structure ◽

Nmr Spectroscopy ◽

1H Nmr ◽

Good Yield ◽

1H Nmr Spectroscopy ◽

X Ray ◽

X Ray Crystallography ◽

Heterocyclic Molecules ◽

Citraconic Anhydride

Our work included a synthesis of three new imine derivatives—1,3-thiazinan-4-one, 1,3-oxazinan-6-one and 1,3-oxazepin-4,7-dione—which contained an adamantyl fragment. These were produced via the condensation of the Schiff`s base (E)-N-(adamantan-1-yl)-1-(3-aryl)methanimine with 3-mercaptopropanoic acid; 3-chloropropanoic acid; and maleic, citraconic anhydride, respectively. These new imines were prepared via the condensation of adamantan-1-ylamine and 3-nitro-, 3-bromobenzaldehyde in n-BuOH. We obtained a good yield of products. FTIR, 1H NMR spectroscopy and C.H.N.S analysis were used to diagnostic the products. The molecular structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine was confirmed by X-ray crystallography analysis.

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New cationic palladium(II) compounds with several bidentate nitrogen-donor ligands: Synthesis, spectroscopic analyses and X-ray crystal structure

Inorganica Chimica Acta ◽

10.1016/j.ica.2005.11.046 ◽

2006 ◽

Vol 359 (7) ◽

pp. 2226-2231 ◽

Cited By ~ 8

Author(s):

Anna Pañella ◽

Josefina Pons ◽

Jordi Garcia-Anton ◽

Xavier Solans ◽

Mercè Font-Bardia ◽

...

Keyword(s):

Crystal Structure ◽

Donor Ligands ◽

Nitrogen Donor Ligands ◽

X Ray ◽

Spectroscopic Analyses ◽

Nitrogen Donor ◽

Cationic Palladium

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Crystalline magnesium chloride–electron donor complexes: new support materials for Ziegler–Natta catalysts

Dalton Transactions ◽

10.1039/c7dt00193b ◽

2017 ◽

Vol 46 (13) ◽

pp. 4452-4460 ◽

Cited By ~ 6

Author(s):

V. H. Nissinen ◽

I. O. Koshevoy ◽

T. T. Pakkanen

Keyword(s):

Crystal Structure ◽

Structure Formation ◽

Magnesium Chloride ◽

Donor Ligands ◽

Nitrogen Donor Ligands ◽

Support Materials ◽

Polymerization Catalyst ◽

Nitrogen Donor ◽

Crystal Structure Formation ◽

Ziegler Natta Catalysts

Chelating oxygen and nitrogen donor ligands (1,2-dimethoxyethane, 1,3-dimethoxypropane, and N,N′-diethylethylenediamine) are found to dictate the crystal structure formation of MgCl2, the important support component of a polymerization catalyst.

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Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4′-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands

Journal of Inorganic Biochemistry ◽

10.1016/j.jinorgbio.2007.02.002 ◽

2007 ◽

Vol 101 (6) ◽

pp. 881-892 ◽

Cited By ~ 149

Author(s):

Michael Devereux ◽

Denis O Shea ◽

Andrew Kellett ◽

Malachy McCann ◽

Maureen Walsh ◽

...

Keyword(s):

Crystal Structures ◽

Donor Ligands ◽

Anticancer Activities ◽

Nitrogen Donor Ligands ◽

X Ray ◽

Nitrogen Donor

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2-(3,5-Dimethyl-1H-pyrazol-1-yl)thiazolo[4,5-b]pyridine

Molbank ◽

10.3390/m1077 ◽

2019 ◽

Vol 2019 (3) ◽

pp. M1077

Author(s):

Lan ◽

Zheng ◽

Wang

Keyword(s):

Nmr Spectroscopy ◽

Single Crystal ◽

1H Nmr ◽

Structure Determination ◽

1H Nmr Spectroscopy ◽

Pyrazole Ring ◽

Hydrogen Atoms ◽

X Ray ◽

X Ray Crystallography

The compound 2-(3,5-dimethyl-1H-pyrazol-1-yl)thiazolo[4,5-b]pyridine (1) was synthesized with a yield of 71% by the reaction of 1-(thiazolo[4,5-b]pyridine-2-yl)hydrazine and acetylacetone. The structure was characterized by a single-crystal X-ray structure determination as well as 1H and 13C{1H} NMR spectroscopy. X-ray crystallography on 1 confirms the molecule consists of a pyridine–thiazole moiety and the pyrazole ring, and all non-hydrogen atoms are planar.

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