Transition metal-catalyzed C–H bond functionalization in multicomponent reactions: a tool toward molecular diversity

2017 ◽  
Vol 15 (43) ◽  
pp. 9031-9043 ◽  
Author(s):  
Jie-Ping Wan ◽  
Lu Gan ◽  
Yunyun Liu
Keyword(s):  
Transition Metal ◽  
Multicomponent Reactions ◽  
Molecular Diversity ◽  
Bond Functionalization ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Research advances in transition metal-catalyzed multicomponent C–H functionalization reactions over the last decade are summarized.

Transition-Metal-Catalyzed Reactions Involving Arynes

Synthesis ◽  
2017 ◽  
Vol 50 (01) ◽  
pp. 1-16 ◽  
Author(s):  
Santosh Mhaske ◽  
Ranjeet Dhokale
Keyword(s):  
Natural Products ◽  
Transition Metal ◽  
Total Synthesis ◽  
Scientific Community ◽  
Multicomponent Reactions ◽  
Polycyclic Aromatic Compounds ◽  
Polycyclic Aromatic ◽  
Transition Metal Catalyzed ◽  
Catalyzed Reactions ◽  
Metal Catalyzed

The plethora of transformations attainable by the transition-metal-catalyzed reactions of arynes has found immense contemporary interest in the scientific community. This review highlights the scope and importance of transition-metal-catalyzed aryne reactions in the field of synthetic organic chemistry reported to date. It covers transformations achieved by the combination of arynes and various transition metals, which provide a facile access to a biaryl motif, fused polycyclic aromatic compounds, different novel carbocycles, various heterocycles, and complex natural products.1 Introduction2 Insertion of Arynes3 Annulation of Arynes4 Cycloaddition of Arynes5 Multicomponent Reactions of Arynes6 Miscellaneous Reactions of Arynes7 Total Synthesis of Natural Products Using Arynes8 Conclusion

Facile Non-Transition Metal-Catalyzed Synthesis of 2-Thioxo-2,3-dihydroquinazolin-4(1H )-one Derivatives via One-Pot Multicomponent Reactions

2019 ◽  
Vol 4 (1) ◽  
pp. 100-104 ◽  
Author(s):  
Saeed Bahadorikhalili ◽  
Golnaz Rahimzadeh ◽  
Ebrahim Kianmehr ◽  
Samira Ansari ◽  
Haleh Hamedifar ◽  
...  
Keyword(s):  
Transition Metal ◽  
Multicomponent Reactions ◽  
One Pot ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals Advances in the Synthesis of Fluorinated Scaffolds by Transition Metal-Catalyzed C–H Bond Activation

2020 ◽  
Vol 74 (11) ◽  
pp. 871-877
Author(s):  
Sara Mazeh ◽  
Maria Ivana Lapuh ◽  
Tatiana Besset
Keyword(s):  
Transition Metal ◽  
Fluorine Atom ◽  
Bond Activation ◽  
Value Added ◽  
Bond Functionalization ◽  
Present Account ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Thanks to the unique features of the fluorine atom and the fluorinated groups, fluorine-containing molecules are essential. Therefore, the search for new fluorinated groups as well as straightforward and original methodologies for their installation is of prime importance. Especially, the combination of organofluorine chemistry with transition metal-catalyzed C–H bond functionalization reactions offered straightforward tools to access original fluorinated scaffolds. In this context, over the last years, our group focused on the development of original methodologies to synthesize fluorine-containing molecules with a special attention to emergent fluorinated groups. The present account highlights our recent contributions to the synthesis of highly value-added fluorine-containing compounds by transition metal-catalyzed C–H bond activation.

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