scholarly journals Continuous flow synthesis of indoles by Pd-catalyzed deoxygenation of 2-nitrostilbenes with carbon monoxide

RSC Advances ◽  
2017 ◽  
Vol 7 (17) ◽  
pp. 10469-10478 ◽  
Author(s):  
Gabriel Glotz ◽  
Bernhard Gutmann ◽  
Paul Hanselmann ◽  
Anna Kulesza ◽  
Dominique Roberge ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Continuous Flow ◽  
Side Product ◽  
Flow Synthesis ◽  
Reaction Proceeds ◽  
Palladium Catalyzed

The palladium-catalyzed cyclization of o-vinylnitrobenzenes employing carbon monoxide as terminal reductant is investigated. The reaction proceeds with 1 to 2 mol% of Pd(OAc)2 and generates carbon dioxide as the only stoichiometric side-product.

Intermolecular C–H Amidation of Alkenes with Carbon Monoxide and Azides via Tandem Palladium Catalysis

Synthesis ◽  
2021 ◽  
Author(s):  
Zheng-Yang Gu ◽  
Yang Wu ◽  
Feng Jin ◽  
Bao Xiaoguang ◽  
Ji-Bao Xia
Keyword(s):  
Carbon Monoxide ◽  
Palladium Catalysis ◽  
Computational Studies ◽  
Organic Azides ◽  
Reaction Proceeds ◽  
Palladium Catalyzed ◽  
Directing Group ◽  
And Control

An atom- and step-economic intermolecular multi-component palladium-catalyzed C–H amidation of alkenes with carbon monoxide and organic azides has been developed for the synthesis of alkenyl amides. The reaction proceeds efficiently without an ortho-directing group on the alkene substrates. Nontoxic dinitrogen is generated as the sole by-product. Computational studies and control experiments have revealed that the reaction takes place via an unexpected mechanism by tandem palladium catalysis.

Continuous Flow Synthesis of Ketones from Carbon Dioxide and Organolithium or Grignard Reagents

2014 ◽  
Vol 126 (32) ◽  
pp. 8556-8560 ◽  
Author(s):  
Jie Wu ◽  
Xiaoqing Yang ◽  
Zhi He ◽  
Xianwen Mao ◽  
T. Alan Hatton ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Continuous Flow ◽  
Grignard Reagents ◽  
Flow Synthesis

scholarly journals Continuous‐flow Synthesis of Aryl Aldehydes by Pd‐catalyzed Formylation of Aryl Bromides Using Carbon Monoxide and Hydrogen

ChemSusChem ◽  
2018 ◽  
Vol 12 (1) ◽  
pp. 326-337 ◽  
Author(s):  
Christopher A. Hone ◽  
Pavol Lopatka ◽  
Rachel Munday ◽  
Anne O'Kearney‐McMullan ◽  
C. Oliver Kappe
Keyword(s):  
Carbon Monoxide ◽  
Continuous Flow ◽  
Flow Synthesis ◽  
Aryl Aldehydes ◽  
Aryl Bromides

scholarly journals Continuous-Flow Synthesis and Derivatization of Aziridines through Palladium-Catalyzed C(sp3)−H Activation

2016 ◽  
Vol 128 (31) ◽  
pp. 9024-9029 ◽  
Author(s):  
Jacek Zakrzewski ◽  
Adam P. Smalley ◽  
Mikhail A. Kabeshov ◽  
Matthew J. Gaunt ◽  
Alexei A. Lapkin
Keyword(s):  
Continuous Flow ◽  
Flow Synthesis ◽  
Palladium Catalyzed

scholarly journals Continuous-Flow Synthesis and Derivatization of Aziridines through Palladium-Catalyzed C(sp3)−H Activation

2016 ◽  
Vol 55 (31) ◽  
pp. 8878-8883 ◽  
Author(s):  
Jacek Zakrzewski ◽  
Adam P. Smalley ◽  
Mikhail A. Kabeshov ◽  
Matthew J. Gaunt ◽  
Alexei A. Lapkin
Keyword(s):  
Continuous Flow ◽  
Flow Synthesis ◽  
Palladium Catalyzed

scholarly journals Continuous flow synthesis of aryl aldehydes by Pd-catalyzed formylation of phenol-derived aryl fluorosulfonates using syngas

RSC Advances ◽  
2020 ◽  
Vol 10 (38) ◽  
pp. 22449-22453
Author(s):  
Manuel Köckinger ◽  
Paul Hanselmann ◽  
Guixian Hu ◽  
Christopher A. Hone ◽  
C. Oliver Kappe
Keyword(s):  
Carbon Monoxide ◽  
Continuous Flow ◽  
Flow Synthesis ◽  
Aryl Aldehydes

Pd-catalyzed formylation of aryl fluorosulfonates by using syngas as an atom efficient and sustainable source of carbon monoxide and hydrogen.

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