scholarly journals Synthesis of poly(n-hexyl methacrylate)-b-poly(methyl methacrylate) via anionic polymerization with t-BuOK as the initiator at ambient temperature

RSC Advances ◽  
2017 ◽  
Vol 7 (85) ◽  
pp. 53996-54001 ◽  
Author(s):  
Anna Zheng ◽  
Ling Su ◽  
Zheng Li ◽  
Guijin Zou ◽  
Xiang Xu ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Ambient Temperature ◽  
Anionic Polymerization ◽  
Initiation Mechanism ◽  
Poly Methyl Methacrylate ◽  
Hexyl Methacrylate

Initiation mechanism of t-BuOK on anionic polymerization of n-HMA in THF.

scholarly journals Synthesis and post-polymerization reaction of end-clickable stereoregular polymethacrylates via termination of stereospecific living anionic polymerization

2015 ◽  
Vol 6 (7) ◽  
pp. 1078-1087 ◽  
Author(s):  
Yasuhiro Kohsaka ◽  
Takashi Kurata ◽  
Kazuki Yamamoto ◽  
Shoya Ishihara ◽  
Tatsuki Kitayama
Keyword(s):  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Polymerization Reaction ◽  
Living Anionic Polymerization ◽  
Poly Methyl Methacrylate ◽  
End Groups

Poly(methyl methacrylate)s with high stereoregularity and clickable end-groups were synthesized via terminating reactions with α-(halomethyl)acrylates in stereospecific living anionic polymerization.

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