Metal-free branched alkyl tetrathienoacene (TTAR)-based sensitizers for high-performance dye-sensitized solar cells

2017 ◽  
Vol 5 (24) ◽  
pp. 12310-12321 ◽  
Author(s):  
Yamuna Ezhumalai ◽  
Byunghong Lee ◽  
Miao-Syuan Fan ◽  
Boris Harutyunyan ◽  
Kumaresan Prabakaran ◽  
...  

New branched alkyl tetrathienothiophene (TTAR)-based organic sensitizers with power conversion efficiency up to 11%.

2015 ◽  
Vol 127 (20) ◽  
pp. 6092-6096 ◽  
Author(s):  
Zhaoyang Yao ◽  
Min Zhang ◽  
Renzhi Li ◽  
Lin Yang ◽  
Yongna Qiao ◽  
...  

2008 ◽  
Vol 8 (9) ◽  
pp. 4761-4766 ◽  
Author(s):  
Dong Wook Kim ◽  
Jin Joo Choi ◽  
Man Ku Kang ◽  
Yongku Kang ◽  
Changjin Lee

We prepared organic sensitizers (S1 and S2) containing julolidine moiety as a donor, phenyl or phenylene thiophene units as a conjugation bridge, and cyano acetic acid as an acceptor for dye sensitized solar cells. S1 exhibited two absorption maxima at 441 nm (ε = 26 200) and 317 nm (ε = 15 500) due to the π–π* transition of the dye molecule. S2 dyes with an additional thiophene unit showed the absorption maximum extended by 18 nm. DSSCs based on S1 dye achieved 2.66% of power conversion efficiency with 8.3 mA cm−2 of short circuit current, 576 mV of open circuit voltage, and 0.56 of fill factor. DSSCs using S2 dye with a longer conjugation attained only 1.48% of power conversion efficiency. The 0.21 V lower driving force for regeneration of the S2 dye compared to the S1 dye is one of the reasons for low conversion efficiency of the S2 dye.


2020 ◽  
Vol 56 (37) ◽  
pp. 5042-5045 ◽  
Author(s):  
Lingling Tao ◽  
Zhe Sun ◽  
Lei Chen ◽  
Mao Liang ◽  
Song Xue

The combination of a zinc stannate photoanode and cobalt complex electrolyte in DSCs yields an impressive power conversion efficiency of 8.1%.


2017 ◽  
Vol 19 (42) ◽  
pp. 28579-28587 ◽  
Author(s):  
Mohammad Adil Afroz ◽  
Keval K. Sonigara ◽  
Telugu Bhim Raju ◽  
Saurabh S. Soni ◽  
Parameswar Krishnan Iyer

The study on specific positions of fluorine substitution on phenylene spacer in organic dyes illustrated that ortho-substitution resulted in the improved power conversion efficiency of >4%.


2014 ◽  
Vol 13 (04) ◽  
pp. 1440006 ◽  
Author(s):  
E. N. Jayaweera ◽  
C. S. K. Ranasinghe ◽  
G. R. A. Kumara ◽  
R. M. G. Rajapakse

SnO 2/ MgO composite film-based dye-sensitized solar cells (DSCs), sensitized with both N719 dye and metal-free D358 dye, employing [Formula: see text] redox couple-based liquid electrolyte, show superior performance to those sensitized with only D358 dye, and N719 dye. A significant improvement in the power conversion efficiency was attained by co-sensitizing the N719-based DSCs with metal-free D358 dye when compared to those obtained for DSCs with individual dyes. As confirmed by UV-visible absorption spectra, N719 dye adsorption is more prominent than that of D358 dye when sensitizing the SnO 2/ MgO composite film with the two dyes, D358 and N719. However, N719 and D358 dyes, when used alone, are prone to form aggregates on the SnO 2/ MgO composite film, when N719 dye is used together with D358, the latter effectively suppresses the aggregation of N719 dye on the SnO 2/ MgO composite film, thereby enhancing the power conversion efficiency of the DSCs. Hence, the corresponding power conversion efficiency of the SnO 2/ MgO composite film-based DSCs can be significantly improved by sensitizing with both N719 and D358 dyes. The reported power conversion efficiencies for the SnO 2/ MgO composite film-based DSCs, sensitized with, (a) D358 dye, (b) N719 dye, and (c) both N719 dye and D358 dye, are 6.37%, 7.43% and 8.60% respectively, under AM 1.5 illumination.


2015 ◽  
Vol 3 (6) ◽  
pp. 3103-3112 ◽  
Author(s):  
Yong Hua ◽  
Jian He ◽  
Caishun Zhang ◽  
Chunjiang Qin ◽  
Liyuan Han ◽  
...  

A series of thiadiazolo[3,4-c]pyridine-cored organic sensitizers has been prepared for DSSC applications. The structural optimization with π-conjugated spacers enhanced the power conversion efficiency to 6.30% from 2.86%.


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