Induced circular dichroism of monoatomic anions: silica-assisted the transfer of chiral environment from molecular assembled nanohelices to halide ions

2018 ◽  
Vol 54 (73) ◽  
pp. 10244-10247 ◽  
Author(s):  
Yutaka Okazaki ◽  
Naoya Ryu ◽  
Thierry Buffeteau ◽  
Shaheen Pathan ◽  
Shoji Nagaoka ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Chemical Reaction ◽  
Halide Ions ◽  
Induced Circular Dichroism ◽  
Circular Dichroïsm ◽  
Chirality Induction

Induced CD of monoatomic anions was detected using silica-coated molecular assembled nanohelices and multi-step chirality induction was achieved through an in situ chemical reaction via chiralized monoatomic anions.

scholarly journals Synthesis of a sucrose dimer with enone tether; a study on its functionalization

2014 ◽  
Vol 10 ◽  
pp. 1246-1254 ◽  
Author(s):  
Zbigniew Pakulski ◽  
Norbert Gajda ◽  
Magdalena Jawiczuk ◽  
Jadwiga Frelek ◽  
Piotr Cmoch ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Double Bond ◽  
Carbonyl Group ◽  
Osmium Tetroxide ◽  
Cd Spectroscopy ◽  
Allylic Alcohol ◽  
Circular Dichroïsm

The reaction of appropriately functionalized sucrose phosphonate with sucrose aldehyde afforded a dimer composed of two sucrose units connected via their C6-positions (‘the glucose ends’). The carbonyl group in this product (enone) was stereoselectively reduced with zinc borohydride and the double bond (after protection of the allylic alcohol formed after reduction) was oxidized with osmium tetroxide to a diol. Absolute configurations of the allylic alcohol as well as the diol were determined by circular dichroism (CD) spectroscopy using the in situ dimolybdenum methodology.

A β-cyclodextrin–resveratrol inclusion complex and the role of geometrical and electronic effects on its electronic induced circular dichroism

RSC Advances ◽  
2013 ◽  
Vol 3 (26) ◽  
pp. 10242 ◽  
Author(s):  
Eduardo Troche-Pesqueira ◽  
Ignacio Pérez-Juste ◽  
Armando Navarro-Vázquez ◽  
María Magdalena Cid
Keyword(s):  
Circular Dichroism ◽  
Inclusion Complex ◽  
Induced Circular Dichroism ◽  
Electronic Effects ◽  
Circular Dichroïsm

Induced circular dichroism of azulene

1980 ◽  
Vol 70 (1) ◽  
pp. 22-26 ◽  
Author(s):  
Akio Tajiri ◽  
Hidemi Hirayama ◽  
Masahiro Hatano
Keyword(s):  
Circular Dichroism ◽  
Induced Circular Dichroism ◽  
Circular Dichroïsm

In situ multifrequency ferromagnetic resonance and x-ray magnetic circular dichroism investigations on Fe/GaAs(110): Enhanced g-factor

2012 ◽  
Vol 100 (9) ◽  
pp. 092402 ◽  
Author(s):  
F. M. Römer ◽  
M. Möller ◽  
K. Wagner ◽  
L. Gathmann ◽  
R. Narkowicz ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Ferromagnetic Resonance ◽  
Magnetic Circular Dichroism ◽  
G Factor ◽  
X Ray ◽  
Circular Dichroïsm

Annealing-Induced Circular Dichroism Enhancement in Luminescent Conjugated Polymers with an Intramolecular Stack Structure

2017 ◽  
Vol 50 (17) ◽  
pp. 6433-6438 ◽  
Author(s):  
Young-Jae Jin ◽  
Kyo-Un Seo ◽  
Young-Ghil Choi ◽  
Masahiro Teraguchi ◽  
Toshiki Aoki ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Conjugated Polymers ◽  
Induced Circular Dichroism ◽  
Circular Dichroïsm
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