Synthesis and magnetic studies of pentagonal bipyramidal metal complexes of Fe, Co and Ni
Three mononuclear model complexes with pentagonal bipyramidal geometry, [MII(L-N3O2)(MeCN)2][BPh4]2 (M = Fe, 1; Co, 2; Ni, 3) were isolated and found to exhibit large uniaxial (1 and 3) and easy-plane (2) magnetic anisotropy, respectively.
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