Interaction of pyridine π-bridge-based poly(methacrylate) dyes for the fabrication of dye-sensitized solar cells with the influence of different strength phenothiazine, fluorene and anthracene sensitizers as donor units with new anchoring mode

2018 ◽  
Vol 42 (22) ◽  
pp. 17939-17949 ◽  
Author(s):  
Gopi Prakash ◽  
Kathavarayan Subramanian

A simple and low-cost approach for the synthesis of three novel propeller-shaped (D2)–π–A type organic polymer dyes has been developed; a new acceptor and π-bridge (PYN) were used to tune the photoelectric properties: DFT studies.

2014 ◽  
Vol 618 ◽  
pp. 19-23
Author(s):  
Li Guo Jin ◽  
Shuo Wang ◽  
Hong Jie Wang

A series of experiments have been carried out to study on the efficiencies in solar energy materials and solar cells. Dye-sensitized solar cells (DSSCs) are good examples of where the quality of the nanomaterials and their interfacial properties are important to device performance. In this report, Nanometer TiO2sol for coating film was prepared by cooperating hydrothermal colloidal sol with organic polymer dispersing agent (PVA). Nanocrystalline TiO2porous films were prepared by using electro-hydrodynamic technique (EHD). The results show the films prepared by EHD technique have multilevel hierarchical structure, therefore, better optical scattering properties. Different constituent quasi-solid electrolytes with blood mimetic thixotropy were prepared by cooperating ionic liquid electrolyte with nanometer TiO2colloidal sol synthetized by sol-gel method. The resulting Quasi-Solid-State dye-sensitized solar cells consist of nanoporous TiO2Film and the dye N3, show conversion efficiencies up to 3.7 percent (8. 51 percent with a mask).


2020 ◽  
pp. 16-21
Author(s):  
PHITCHAPHORN KHAMMEE ◽  
YUWALEE UNPAPROM ◽  
UBONWAN SUBHASAEN ◽  
RAMESHPRABU RAMARAJ

Recently, dye-sensitized solar cells (DSSC) have concerned significant attention attributable to their material preparation process, architectural and environmental compatibility, also low cost and effective photoelectric conversion efficiency. Therefore, this study aimed to use potential plant materials for DSSC. This research presents the extraction of natural pigments from yellow cotton flowers (Cochlospermum regium). In addition, the natural pigments were revealed that outstanding advantages, including a wide absorption range (visible light), easy extraction method, safe, innocuous pigments, inexpensive, complete biodegradation and ecofriendly. Methanol was used as a solvent extraction for the yellow cotton flower. The chlorophylls and carotenoid pigments extractions were estimated by a UV-visible spectrometer. The chlorophyll-a, chlorophyll-b, and carotenoid yield were 0.719±0.061 µg/ml, 1.484±0.107 µg/ml and 7.743±0.141 µg/ml, respectively. Thus, this study results suggested that yellow cotton flowers containing reasonable amounts appealable in the DSSC production.


Nanoscale ◽  
2014 ◽  
Vol 6 (23) ◽  
pp. 14433-14440 ◽  
Author(s):  
Sheng-qi Guo ◽  
Tian-zeng Jing ◽  
Xiao Zhang ◽  
Xiao-bing Yang ◽  
Zhi-hao Yuan ◽  
...  

In this work, we report the synthesis of mesoporous Bi2S3 nanorods under hydrothermal conditions without additives, and investigated their catalytic activities as the CE in DSCs by I–V curves and tested conversion efficiency.


ACS Omega ◽  
2021 ◽  
Vol 6 (17) ◽  
pp. 11183-11191
Author(s):  
Kezhong Wu ◽  
Yingshan Wu ◽  
Pengyuan Fu ◽  
Dandan Yang ◽  
Bei Ruan ◽  
...  

2012 ◽  
Vol 2012 ◽  
pp. 1-21 ◽  
Author(s):  
Yuancheng Qin ◽  
Qiang Peng

Dye-sensitized solar cells (DSSCs) have attracted considerable attention in recent years due to the possibility of low-cost conversion of photovoltaic energy. The DSSCs-based ruthenium complexes as sensitizers show high efficiency and excellent stability, implying potential practical applications. This review focuses on recent advances in design and preparation of efficient ruthenium sensitizers and their applications in DSSCs, including thiocyanate ruthenium sensitizers and thiocyanate-free ruthenium sensitizers.


2017 ◽  
Vol 2017 ◽  
pp. 1-8
Author(s):  
Saeid Vafaei ◽  
Kazuhiro Manseki ◽  
Soki Horita ◽  
Masaki Matsui ◽  
Takashi Sugiura

We present for the first time a synthetic method of obtaining 1D TiO2 nanorods with sintering methods using bundle-shaped 3D rutile TiO2 particles (3D BR-TiO2) with the dimensions of around 100 nm. The purpose of this research is (i) to control crystallization of the mixture of two kinds of TiO2 semiconductor nanocrystals, that is, 3D BR-TiO2 and spherical anatase TiO2 (SA-TiO2) on FTO substrate via sintering process and (ii) to establish a new method to create photoanodes in dye-sensitized solar cells (DSSCs). In addition, we focus on the preparation of low-cost and environmentally friendly titania electrode by adopting the “water-based” nanofluids. Our results provide useful guidance on how to improve the photovoltaic performance by reshaping the numerous 3D TiO2 particles to 1D TiO2-based electrodes with sintering technique.


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