POTENTIAL EVALUATION OF YELLOW COTTON (COCHLOSPERMUM REGIUM) PIGMENTS FOR DYE SENSITIZED SOLAR CELLS APPLICATION

2020 ◽  
pp. 16-21
Author(s):  
PHITCHAPHORN KHAMMEE ◽  
YUWALEE UNPAPROM ◽  
UBONWAN SUBHASAEN ◽  
RAMESHPRABU RAMARAJ

Recently, dye-sensitized solar cells (DSSC) have concerned significant attention attributable to their material preparation process, architectural and environmental compatibility, also low cost and effective photoelectric conversion efficiency. Therefore, this study aimed to use potential plant materials for DSSC. This research presents the extraction of natural pigments from yellow cotton flowers (Cochlospermum regium). In addition, the natural pigments were revealed that outstanding advantages, including a wide absorption range (visible light), easy extraction method, safe, innocuous pigments, inexpensive, complete biodegradation and ecofriendly. Methanol was used as a solvent extraction for the yellow cotton flower. The chlorophylls and carotenoid pigments extractions were estimated by a UV-visible spectrometer. The chlorophyll-a, chlorophyll-b, and carotenoid yield were 0.719±0.061 µg/ml, 1.484±0.107 µg/ml and 7.743±0.141 µg/ml, respectively. Thus, this study results suggested that yellow cotton flowers containing reasonable amounts appealable in the DSSC production.

2021 ◽  
Vol 261 ◽  
pp. 01046
Author(s):  
Mengdan Chen

With the development of society, the demand for energy is increasing significantly, and the environmental problems are becoming more and more serious. Therefore, it is urgent to find efficient and clean new energy. Among the many new energy sources, solar energy has been favoured most for its universality, harmlessness and low cost. In 1991, the photoelectric conversion efficiency of dye-sensitized solar cells (DSSCs) has been greatly improved, which has attracted the attention. In recent 30 years, the researches on DSSCs have been increasing and expanding. Dye sensitizer is the most important component of DSSC, and also a key issue of researchers. This paper aims to summarize the types, structures and development trends of dye sensitizers, and provide inspiration for us to design and evaluate new dye sensitizers.


2012 ◽  
Vol 430-432 ◽  
pp. 631-635
Author(s):  
Shu Hong Liu ◽  
Gui Shan Liu ◽  
Xiao Yue Shen ◽  
Zhi Qiang Hu

The carbon counter electrodes for Dye-sensitized solar cells (DSSCs) were deposited on FTO glass using graphite target by bipolar pulse magnetron sputtering. The effects of sputtering pressure on the structures and properties for carbon films were investigated. The carbon bond structure was analyzed by Raman spectra. The sheet resistance of carbon film was detected by four-probe tester. The transmittance was tested by UV-visible spectrum. The performance of DSSCs was tested by solar simulator after the cells assembled. The results indicated that the ratio of ID/IG reduced, the degree of graphitization decreased, sheet resistance raised, transmittance increased and photoelectric conversion efficiency reduced with the increasing of sputtering pressure.


2012 ◽  
Vol 629 ◽  
pp. 332-338 ◽  
Author(s):  
Zhi Hua Tian ◽  
Jian Xi Yao ◽  
Mi Na Guli

TiO2 films with three-dimensional web-like structure have been prepared by the photo polymerization-induced phase separation method (PIPS). Scanning electron microscopy and X-ray diffraction were used to characterize the as-prepared TiO2 films. The results showed that the film texture could be tuned by changing the composition of the precursor solution. The TiO2 film with web-like structure exhibited high photocatalytic activity for the degradation of methylene blue (MB) dye. The as-prepared films were used as the photo-anodes in dye-sensitized solar cells (DSCs). The photoelectric conversion efficiency of the DSCs was significantly enhanced by changing the POGTA/TTB in the precursor solution. Because of the increased dye adsorption active sites and efficient electron transport in the TiO2 anode film, a photoelectric conversion efficiency of 3.015% was obtained.


2018 ◽  
Vol 5 (2) ◽  
pp. 171054 ◽  
Author(s):  
J. Llanos ◽  
I. Brito ◽  
D. Espinoza ◽  
Ramkumar Sekar ◽  
P. Manidurai

Y 1.86 Eu 0.14 WO 6 phosphors were prepared using a solid-state reaction method. Their optical properties were analysed, and they was mixed with TiO 2 , sintered, and used as a photoelectrode (PE) in dye-sensitized solar cells (DSSCs). The as-prepared photoelectrode was characterized by photoluminescence spectroscopy, diffuse reflectance, electrochemical impedance spectroscopy (EIS) and X-ray diffraction. The photoelectric conversion efficiency of the DSSC with TiO 2 :Y 1.86 Eu 0.14 WO 6 (100:2.5) was 25.8% higher than that of a DSCC using pure TiO 2 as PE. This high efficiency is due to the ability of the luminescent material to convert ultraviolet radiation from the sun to visible radiation, thus improving the solar light harvesting of the DSSC.


2014 ◽  
Vol 953-954 ◽  
pp. 1095-1098 ◽  
Author(s):  
Jun Zhang ◽  
Ya Han Wu ◽  
Fang Xue ◽  
Meng Jun Yuan ◽  
Yan Huo ◽  
...  

The structural morphology, arrangement of the nanocrystalline particles, porosity factor, surface state, crystalline phase and specific area of photoelectrode film have great influence on photoelectric performance of dye sensitized solar cells (DSSCs). At present, using TiO2 as the photoelectrode in the DSSC material has achieved very good photoelectric conversion efficiency. In this paper, the plating method is adopted to directly deposited the titanium coating on the conductive glass substrate, oxidizing the surface of titanium film, so that it is generated on the surface of titanium dioxide oxidation layer. Making it as the DSSC photoelectrode, obtained relative high photoelectric conversion efficiency.


RSC Advances ◽  
2015 ◽  
Vol 5 (62) ◽  
pp. 50483-50493 ◽  
Author(s):  
Malihe Afrooz ◽  
Hossein Dehghani

In this study, triphenyl phosphate (TPP) is applied as an effective and inexpensive additive in the dye sensitized solar cells (DSSCs) and an increase in the photoelectric conversion efficiency is obtained of almost 24%.


2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Che-Lung Lee ◽  
Wen-Hsi Lee ◽  
Cheng-Hsien Yang

Triazoloisoquinoline-based organic dyestuffs were synthesized and used in the fabrication of dye-sensitized solar cells (DSSCs). After cosensitization with ruthenium complex, the triazoloisoquinoline-based organic dyestuffs overcame the deficiency of ruthenium dyestuff absorption in the blue part of the visible spectrum. This method also fills the blanks of ruthenium dyestuff sensitized TiO2film and forms a compact insulating molecular layer due to the nature of small molecular organic dyestuffs. The incident photon-to-electron conversion efficiency of N719 at shorter wavelength regions is 49%. After addition of a triazoloisoquinoline-based dyestuff for co-sensitization, the IPCE at 350–500 nm increased significantly. This can be attributed to the increased photocurrent of the cells, which improves the dye-sensitized photoelectric conversion efficiency from 6.23% to 7.84%, and the overall conversion efficiency increased by about 26%. As a consequence, this low molecular weight organic dyestuff is a promising candidate as coadsorbent and cosensitizer for highly efficient dye-sensitized solar cells.


2004 ◽  
Vol 836 ◽  
Author(s):  
Douglas A. Gish ◽  
Gregory K. Kiema ◽  
Martin O. Jensen ◽  
Michael J. Brett

ABSTRACTDye sensitized solar cells (DSSCs) were fabricated using porous thin films of TiO2. These films were deposited by electron beam evaporation and an advanced substrate motion technique called PhiSweep. PhiSweep, an extension of glancing angle deposition (GLAD), allows for greater control over the surface area of nanostructured thin films than is possible with traditional GLAD. The as-deposited films were amorphous, so the films were annealed to improve their crystal structure. The films were sensitized with a photoactive dye and implemented into a DSSC configuration as the electron collecting electrode. It was expected that the higher surface area of the films produced using the PhiSweep method would improve the cell performance compared with cells made using traditional GLAD films of TiO2. However, the performance of the cells prepared using PhiSweep films was likely hindered by higher internal resistance of the films compared to the films prepared by traditional GLAD. The highest photoelectric conversion efficiency of the dye sensitized solar cells produced using the PhiSweep method was 1.5%.


Author(s):  
Natsumi Ishii ◽  
Yuji Okamoto ◽  
Yoshikazu Suzuki

MgTiO3, MgTi2O5 and Mg2TiO4 were examined as DSC electrodes to improve photoelectric conversion efficiency. MgCO3 (basic) and TiO2 powders (nominally, Mg:Ti = 1:1, 1:2 and 2:1 in mole fraction) were wet-ball milled in ethanol for 24 h. The mixed powders were calcined in air at 1100 °C for 2 h to obtain the MgTiO3 and MgTi2O5 powders, and at 1300 °C for 2 h to obtain the Mg2TiO4 powder. Single-phase MgTiO3, MgTi2O5 and Mg2TiO4 powders were successfully synthesized. Although the DSC performance was not as high as expected, all samples were functioned as DSC.


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