Anthracene–rhodium complexes with metal coordination at the central ring – a new class of catalysts for reductive amination

A new class of anthracene–metal complexes with central ring coordination was tested in catalysis. A simple and efficient protocol for reductive amination without an external hydrogen source has been developed.

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Ligand Design for Site-Selective Metal Coordination: Synthesis of Transition-Metal Complexes with η6 -Coordination of the Central Ring of Anthracene

Angewandte Chemie International Edition ◽

10.1002/anie.201700685 ◽

2017 ◽

Vol 56 (20) ◽

pp. 5584-5587 ◽

Cited By ~ 4

Author(s):

Eduard E. Karslyan ◽

Alexandra O. Borissova ◽

Dmitry S. Perekalin

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Ligand Design ◽

Metal Coordination ◽

Central Ring ◽

Site Selective

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Ligand Design for Site-Selective Metal Coordination: Synthesis of Transition-Metal Complexes with η6 -Coordination of the Central Ring of Anthracene

Angewandte Chemie ◽

10.1002/ange.201700685 ◽

2017 ◽

Vol 129 (20) ◽

pp. 5676-5679 ◽

Cited By ~ 2

Author(s):

Eduard E. Karslyan ◽

Alexandra O. Borissova ◽

Dmitry S. Perekalin

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Ligand Design ◽

Metal Coordination ◽

Central Ring ◽

Site Selective

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Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination

ACS Catalysis ◽

10.1021/acscatal.5b02916 ◽

2016 ◽

Vol 6 (3) ◽

pp. 2043-2046 ◽

Cited By ~ 30

Author(s):

Oleg I. Afanasyev ◽

Alexey A. Tsygankov ◽

Dmitry L. Usanov ◽

Dmitry S. Perekalin ◽

Nikita V. Shvydkiy ◽

...

Keyword(s):

Metal Complexes ◽

Reductive Amination ◽

New Class

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Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

Inorganic Chemistry Frontiers ◽

10.1039/c9qi01278h ◽

2020 ◽

Vol 7 (3) ◽

pp. 786-794 ◽

Cited By ~ 3

Author(s):

Jingqi Han ◽

Kin-Man Tang ◽

Shun-Cheung Cheng ◽

Chi-On Ng ◽

Yuen-Kiu Chun ◽

...

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Carbene Complexes ◽

New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

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Enantioselective Preparation of Planar‐Chiral Transition Metal Complexes by Asymmetric Olefin‐Metathesis Reactions in Metal Coordination Spheres

The Chemical Record ◽

10.1002/tcr.202100102 ◽

2021 ◽

Author(s):

Masamichi Ogasawara

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Olefin Metathesis ◽

Metal Coordination ◽

Chiral Transition ◽

Metathesis Reactions ◽

Coordination Spheres

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ChemInform Abstract: OXIDATION OF ALCOHOLS BY TRANSITION METAL COMPLEXES. PART III. THE REDUCTION OF ALDIMINES BY HYDROGEN TRANSFER FROM PROPAN-2-OL CATALYZED BY RHODIUM COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.198141144 ◽

1981 ◽

Vol 12 (41) ◽

Author(s):

R. GRIGG ◽

T. R. B. MITCHELL ◽

N. TONGPENYAI

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Hydrogen Transfer ◽

Rhodium Complexes ◽

Oxidation Of Alcohols

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Synthesis of the cyclopentadienone rhodium complexes and investigation of their catalytic activity in the reductive amination of aldehydes in the presence of carbon monoxide

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2017.02.014 ◽

2017 ◽

Vol 835 ◽

pp. 6-11 ◽

Cited By ~ 6

Author(s):

Roman A. Pototskiy ◽

Oleg I. Afanasyev ◽

Yulia V. Nelyubina ◽

Denis Chusov ◽

Alexander R. Kudinov ◽

...

Keyword(s):

Carbon Monoxide ◽

Catalytic Activity ◽

Reductive Amination ◽

Rhodium Complexes

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Metallkomplexe mit biologisch wichtigen Liganden, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylat-Rhodium-Komplexe / Metal Complexes of Biologically Important Ligands, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylate-Rhodium Complexes

Zeitschrift für Naturforschung B ◽

10.1515/znb-2002-0714 ◽

2002 ◽

Vol 57 (7) ◽

pp. 810-818 ◽

Cited By ~ 2

Author(s):

Walter Ponikwar ◽

Peter Mayer ◽

Wolfgang Beck

Keyword(s):

Amino Acids ◽

Metal Complexes ◽

Dynamic Behaviour ◽

Rhodium Complexes ◽

X Ray Diffraction ◽

X Ray ◽

H Nmr

The reactions of [(η3-C3H5)2Rh-μ-Cl]2 with the anions of α-amino acids (glycine, L-alanine, L-valine, L-isoleucine, L-proline, L-phenylalanine, L-phenylglycine, L-thyrosine) afford the N,O-chelates (η3-C3H5)2Rh(α-amino carboxylate). For complex (η3-C3H5)2Rh(glycinate) dynamic behaviour in solution could be observed by 1H NMR. The structure of (η3-C3H5)2Rh(L-prolinate) was determined by X-ray diffraction.

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