Coinage metalides: a new class of excess electron compounds with high stability and large nonlinear optical responses

2020 ◽  
Vol 22 (16) ◽  
pp. 8476-8484
Author(s):  
Xiang-Hui Li ◽  
Xiao-Ling Zhang ◽  
Qiao-Hong Chen ◽  
Li Zhang ◽  
Jing-Hua Chen ◽  
...  
Keyword(s):  
High Stability ◽  
Nonlinear Optical ◽  
Electron Acceptors ◽  
Excess Electron ◽  
Coinage Metal ◽  
New Class ◽  
Optical Responses ◽  
Metal Atoms ◽  
Electron Compounds

A new class of NLO molecules, termed coinage metalides, was designed by using coinage metal atoms as excess electron acceptors.

Can Coinage Metal Atoms Be Capable of Serving as an Excess Electron Source of Alkalides with Considerable Nonlinear Optical Responses?

2017 ◽  
Vol 56 (8) ◽  
pp. 4594-4600 ◽  
Author(s):  
Wei-Ming Sun ◽  
Xiang-Hui Li ◽  
Juan Wu ◽  
Jian-Ming Lan ◽  
Chun-Yan Li ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Electron Source ◽  
Excess Electron ◽  
Coinage Metal ◽  
Optical Responses ◽  
Metal Atoms

A theoretical study on novel alkaline earth-based excess electron compounds: unique alkalides with considerable nonlinear optical responses

2015 ◽  
Vol 17 (6) ◽  
pp. 4524-4532 ◽  
Author(s):  
Wei-Ming Sun ◽  
Di Wu ◽  
Ying Li ◽  
Jia-Yuan Liu ◽  
Hui-Min He ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Nonlinear Optical ◽  
Alkaline Earth ◽  
Theoretical Study ◽  
Excess Electron ◽  
Optical Responses ◽  
Electron Compounds ◽  
Metal Anions

A series of novel excess electron compounds M(NH3)6NaCl and M(NH3)6Na2 (M = Mg and Ca) were designed, in which the lowest-energy M(NH3)6Na2 compounds are the first alkalides containing double alkali metal anions.

Designing a new class of excess electron compounds with unique electronic structures and extremely large non-linear optical responses

2020 ◽  
Vol 44 (16) ◽  
pp. 6411-6419
Author(s):  
Xiang-Hui Li ◽  
Li Zhang ◽  
Xiao-Ling Zhang ◽  
Bi-Lian Ni ◽  
Chun-Yan Li ◽  
...  
Keyword(s):  
Electronic Structures ◽  
Excess Electron ◽  
New Class ◽  
Optical Responses ◽  
Non Linear ◽  
Linear Optical ◽  
Electron Compounds

New Ca+-1-M′− (M′ = Li, Na, and K) compounds with typical alkalide features and electride-like characteristics have been obtained.

Designing Alkalides with Considerable Nonlinear Optical Responses and High Stability Based on the Facially Polarized Janus all-cis-1,2,3,4,5,6-Hexafluorocyclohexane

2017 ◽  
Vol 36 (17) ◽  
pp. 3352-3359 ◽  
Author(s):  
Wei-Ming Sun ◽  
Bi-Lian Ni ◽  
Di Wu ◽  
Jian-Ming Lan ◽  
Chun-Yan Li ◽  
...  
Keyword(s):  
High Stability ◽  
Nonlinear Optical ◽  
Optical Responses

Remarkable second and third order nonlinear optical properties of organometallic C6Li6–M3O electrides

2020 ◽  
Vol 44 (23) ◽  
pp. 9822-9829 ◽  
Author(s):  
Faizan Ullah ◽  
Khurshid Ayub ◽  
Tariq Mahmood
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Excess Electron ◽  
Third Order ◽  
Electron Compounds

Electrides are excess electron compounds with excellent nonlinear optical properties.

Remarkable nonlinear optical response of excess electron compounds: theoretically designed alkali-doped aziridine M–(C2NH5)n

2017 ◽  
Vol 19 (35) ◽  
pp. 23951-23959 ◽  
Author(s):  
Bo Li ◽  
Chao Xu ◽  
Xuan Xu ◽  
Chaoyuan Zhu ◽  
Feng Long Gu
Keyword(s):  
Nonlinear Optical ◽  
Optical Response ◽  
Excess Electron ◽  
Nonlinear Optical Response ◽  
First Hyperpolarizability ◽  
Nlo Response ◽  
Electron Compounds

Newly theoretically designed alkali-doped aziridine M–(C2NH5)4 shows a remarkable NLO response and its first hyperpolarizability is 10 to 100 times larger than those of M@Calix[4]pyrrole.

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