dz2 orbital character of polyhedra in complex solid-state transition-metal compounds

2020 ◽  
Vol 49 (2) ◽  
pp. 431-437 ◽  
Author(s):  
Isao Ohkubo ◽  
Takao Mori
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Electronic Structures ◽  
State Transition ◽  
Transition Metal Compounds ◽  
Metal Compounds ◽  
Solid State Transition ◽  
Edge Sharing Octahedra ◽  
Orbital Character ◽  
Trigonal Prismatic

dz2 orbitals of the transition metals make major contributions to electronic structures near the Fermi levels in d0-, d1-complex transition-metal compounds containing face-sharing, edge-sharing octahedra, or edge-sharing trigonal prismatic layers.

Structural Variation of Dinuclear Transition Metal Compounds with a Common Type of Ligand:  Solid State and Solution Structures and Model Studies

1999 ◽  
Vol 38 (7) ◽  
pp. 1416-1421 ◽  
Author(s):  
Peter Comba ◽  
Sergey P. Gavrish ◽  
Robert W. Hay ◽  
Peter Hilfenhaus ◽  
Yaroslaw D. Lampeka ◽  
...  
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Structural Variation ◽  
Common Type ◽  
Transition Metal Compounds ◽  
Metal Compounds ◽  
Solution Structures ◽  
Model Studies
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