Transition-metal free C3-amidation of quinoxalin-2(1H)-ones using Selectfluor as a mild oxidant

An efficient and convenient protocol for the synthesis of 3-amidated quinoxalin-2(1H)-ones was developed via transition-metal free direct oxidative amidation of quinoxalin-2(1H)-ones with amidates using Selectfluor reagent as a mild oxidant.

ChemInform Abstract: Transition-Metal-Free Oxidative Amidation of Benzyl Alcohols with Amines Catalyzed by NaI: A New Method for the Synthesis of Benzamides.

ChemInform ◽

10.1002/chin.201510098 ◽

2015 ◽

Vol 46 (10) ◽

pp. no-no

Author(s):

Meghdad Karimi ◽

Dariush Saberi ◽

Kobra Azizi ◽

Marzban Arefi ◽

Akbar Heydari

Keyword(s):

Transition Metal ◽

New Method ◽

Benzyl Alcohols ◽

Metal Free ◽

ChemInform Abstract: Synthesis of Amides Through an Oxidative Amidation of Tetrazoles with Aldehydes under Transition-Metal-Free Conditions.

ChemInform ◽

10.1002/chin.201517103 ◽

2015 ◽

Vol 46 (17) ◽

pp. no-no

Author(s):

Juan Du ◽

Kai Luo ◽

Xiuli Zhang

Keyword(s):

Transition Metal ◽

Metal Free ◽

Synthesis of amides through an oxidative amidation of tetrazoles with aldehydes under transition-metal-free conditions

RSC Advances ◽

10.1039/c4ra07658c ◽

2014 ◽

Vol 4 (97) ◽

pp. 54539-54546 ◽

Cited By ~ 7

Author(s):

Juan Du ◽

Kai Luo ◽

Xiuli Zhang

Keyword(s):

Transition Metal ◽

Efficient Synthesis ◽

Metal Free ◽

An inexpensive and efficient synthesis of amides was developed via directly oxidative amidation of tetrazoles with aldehydes under transition-metal-free conditions.

Transition-metal-free oxidative amidation of benzyl alcohols with amines catalyzed by NaI: a new method for the synthesis of benzamides

Tetrahedron Letters ◽

10.1016/j.tetlet.2014.07.085 ◽

2014 ◽

Vol 55 (39) ◽

pp. 5351-5353 ◽

Cited By ~ 18

Author(s):

Meghdad Karimi ◽

Dariush Saberi ◽

Kobra Azizi ◽

Marzban Arefi ◽

Akbar Heydari

Keyword(s):

Transition Metal ◽

New Method ◽

Benzyl Alcohols ◽

Metal Free ◽

Transition-metal-free catalytic hydroboration reduction of amides to amines

Organic Chemistry Frontiers ◽

10.1039/d0qo01092h ◽

2020 ◽

Vol 7 (21) ◽

pp. 3515-3520

Author(s):

Wubing Yao ◽

Jiali Wang ◽

Aiguo Zhong ◽

Shiliang Wang ◽

Yinlin Shao

Keyword(s):

Transition Metal ◽

Selective Catalytic Reduction ◽

Catalytic Reduction ◽

Value Added ◽

The selective catalytic reduction of amides to value-added amine products is a desirable but challenging transformation.

Deaminative carbonylative thioesterification of activated alkylamines with thiophenols under transition-metal-free conditions

Organic Chemistry Frontiers ◽

10.1039/d0qo01479f ◽

2021 ◽

Author(s):

Fengqian Zhao ◽

Xiao-Feng Wu

Keyword(s):

Free Radical ◽

Transition Metal ◽

A transition-metal-free radical carbonylation of activated alkylamines with thiophenols has been successfully developed. Various thioesters were selectively produced with moderate to good yields.

Regioselective C3-H Trifluoromethylation of 2H-Indazole Under Transition-Metal-Free Photoredox Catalysis

10.26434/chemrxiv.7796603.v1 ◽

2019 ◽

Cited By ~ 1

Author(s):

Arumugavel Murugan ◽

Venkata Nagarjuna Babu ◽

Nagaraj Sabarinathan ◽

Sharada Duddu. S

Keyword(s):

Transition Metal ◽

Visible Light ◽

Practical Approach ◽

Hypervalent Iodine ◽

Radical Mechanism ◽

Photoredox Catalysis ◽

Here we report a visible-light-promoted metal-free regioselective C3-H trifluoromehtylation reaction that proceeds via radical mechanism and which supported by control experiments. The combination of photoredox catalysis and hypervalent iodine reagent provides a practical approach for the present trifluoromethylation reaction and synthesis of a library of trifluoromethylated indazoles.

Selective Oxidation of Alcohols Catalyzed by a Transition Metal-Free System of NHPI/DDQ/NaNO2

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) ◽

10.3724/sp.j.1088.2011.00734 ◽

2011 ◽

Vol 32 (1) ◽

pp. 118-122 ◽

Cited By ~ 2

Author(s):

Lipeng ZHOU ◽

Chaofeng ZHANG ◽

Tao FANG ◽

Bingbing ZHANG ◽

Ying WANG ◽

...

Keyword(s):

Transition Metal ◽

Selective Oxidation ◽

Free System ◽

Metal Free ◽

Oxidation Of Alcohols

Defect engineering and characterization of active sites for efficient electrocatalysis

Nanoscale ◽

10.1039/d0nr08976a ◽

2021 ◽

Vol 13 (6) ◽

pp. 3327-3345

Author(s):

Xuecheng Yan ◽

Linzhou Zhuang ◽

Zhonghua Zhu ◽

Xiangdong Yao

Keyword(s):

Transition Metal ◽

Active Sites ◽

Defect Engineering ◽

This review highlights recent advancements in defect engineering and characterization of both metal-free carbons and transition metal-based electrocatalysts.

Transition metal free, green and facile halogenation of ketene dithioacetals using a KX–oxidant system

New Journal of Chemistry ◽

10.1039/d0nj03737k ◽

2021 ◽

Author(s):

Vishakha Rai ◽

Ganesh Shivayogappa Sorabad ◽

Mahagundappa Rachappa Maddani

Keyword(s):

Transition Metal ◽

Ambient Temperature ◽

Metal Free ◽

Ketene Dithioacetals ◽

System P ◽

Oxidative Halogenation ◽

Potassium Halide

A facile oxidative halogenation of α-oxo ketene dithioacetals is achieved by using a potassium halide and an oxidant combination under transition metal free conditions at ambient temperature.