scholarly journals Anharmonic kinetics of the cyclopentane reaction with hydroxyl radical

2020 ◽  
Vol 11 (9) ◽  
pp. 2511-2523 ◽  
Author(s):  
Junjun Wu ◽  
Lu Gem Gao ◽  
Wei Ren ◽  
Donald G. Truhlar

Quadratic–quartic bend anharmonicity and torsional anharmonicities play important roles in the kinetics of a cyclic hydrocarbon.

2021 ◽  
pp. 128068
Author(s):  
Martin Walter ◽  
Gerald Geroldinger ◽  
Lars Gille ◽  
Stephan M. Kraemer ◽  
Walter D.C. Schenkeveld

2002 ◽  
Vol 15 (5) ◽  
pp. 287-292 ◽  
Author(s):  
Hugo Destaillats ◽  
Adrián G. Turjanski ◽  
Darío A. Estrin ◽  
Michael R. Hoffmann

2007 ◽  
Vol 111 (19) ◽  
pp. 3932-3950 ◽  
Author(s):  
Ahren W. Jasper ◽  
Stephen J. Klippenstein ◽  
Lawrence B. Harding ◽  
Branko Ruscic

1981 ◽  
Vol 85 (20) ◽  
pp. 2913-2916 ◽  
Author(s):  
J. M. Nicovich ◽  
R. L. Thompson ◽  
A. R. Ravishankara
Keyword(s):  

An apparatus for effecting flash photolysis in the vacuum ultra-violet region is described. Appreciable decompositions of water, carbon dioxide, acetylene, ethylene and methane were effected with a 2000 J flash of 30 p .s duration. A detailed study of water vapour photolysis has established that, in the primary step, at least 90 % of the dissociation leads to a hydrogen atom and a hydroxyl radical. The kinetics of the hydroxyl radical disappearance, following flash photolysis of water vapour in the presence of various third bodies, has been studied. The rate constant is faster in xenon than in helium and other similarities with the data on iodine atom recombination suggest the operation of a mechanism involving intermediate complex formation.


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