Temporally resolved thermal desorption of volatile organics from nanoporous silica preconcentrator

The Analyst ◽  
2021 ◽  
Vol 146 (1) ◽  
pp. 109-117
Author(s):  
William Winter ◽  
Coco Day ◽  
Joshua Prestage ◽  
Tanya Hutter
Keyword(s):  
Volatile Organic Compounds ◽  
Gas Phase ◽  
Organic Compounds ◽  
Thermal Desorption ◽  
Nanoporous Silica ◽  
Volatile Organics ◽  
Desorption Temperature ◽  
Volatile Organic

Gas-phase volatile organic compounds (VOCs) are collected in a nanoporous silica preconcentrator, then released slowly by heating onto a detector. Desorption temperature depends on VOC properties, allowing potential discrimination.

The rate of photocatalytic oxidation of aromatic volatile organic compounds in the gas-phase

2008 ◽  
Vol 42 (34) ◽  
pp. 7844-7850 ◽  
Author(s):  
Aikaterini K. Boulamanti ◽  
Christos A. Korologos ◽  
Constantine J. Philippopoulos
Keyword(s):  
Volatile Organic Compounds ◽  
Gas Phase ◽  
Organic Compounds ◽  
Photocatalytic Oxidation ◽  
Volatile Organic

Characterization of thermal desorption with the Deans-switch technique in gas chromatographic analysis of volatile organic compounds

2016 ◽  
Vol 1462 ◽  
pp. 107-114
Author(s):  
Chang-Feng Ou-Yang ◽  
Ying-Xue Huang ◽  
Ting-Jyun Huang ◽  
Yong-Shen Chen ◽  
Chieh-Heng Wang ◽  
...  
Keyword(s):  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Thermal Desorption ◽  
Chromatographic Analysis ◽  
Gas Chromatographic Analysis ◽  
Volatile Organic ◽  
Deans Switch

Optimisation of secondary electrospray ionisation (SESI) for the trace determination of gas-phase volatile organic compounds

The Analyst ◽  
2010 ◽  
Vol 135 (2) ◽  
pp. 306 ◽  
Author(s):  
Leonard A. Dillon ◽  
Victoria N. Stone ◽  
Laura A. Croasdell ◽  
Peter R. Fielden ◽  
Nicholas J. Goddard ◽  
...  
Keyword(s):  
Volatile Organic Compounds ◽  
Gas Phase ◽  
Organic Compounds ◽  
Trace Determination ◽  
Electrospray Ionisation ◽  
Volatile Organic

Application of carbon monolith based on exfoliated graphite for sorption and subsequent chromatographic determination of volatile organic compounds in soil air

2021 ◽  
Vol 87 (11) ◽  
pp. 5-10
Author(s):  
E. S. Markova ◽  
A. V. Pirogov ◽  
A. A. Sadovnikova ◽  
M. V. Popik ◽  
O. A. Shpigun ◽  
...  
Keyword(s):  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Thermal Desorption ◽  
Carbon Adsorbent ◽  
Chromatographic Determination ◽  
State University ◽  
Soil Air ◽  
Carbon Monolith ◽  
Volatile Organic ◽  
Chromatographic Peaks

The possibility of using a new graphene-based carbon monolith for searching new oil deposits or branches adjacent to the already registered oilfields by areal geochemical survey is demonstrated. The material has been developed at the Faculty of Chemistry of M. V. Lomonosov Moscow State University. Sorption of volatile organic compounds (VOCs) from soil air at the oilfield was carried out using two sorbents (carbon adsorbent and Tenax-TA traditionally used for such analyses) with subsequent determination by gas chromatography with mass spectrometric detection and thermal desorption as a way of sample injection (TD/GC/MS). The new material absorbs more hydrocarbons (n-alkanes and monoaromatics) in the range from C8 to C16 than Tenax-TA, the intensities of the chromatographic peaks of the compounds also being higher. The phenomenon of irreversible sorption from carbon materials is observed for VOCs from C17 and more. However, the concentration of such substances in the soil air is rather low due to the low pressure of saturated vapors of these compounds under normal conditions. Hence, the chromatogram of carbon monolith reflects the macro-characteristics of this oil deposit better than Tenax-TA. To increase the sensitivity of the determination, a preliminary optimization of thermal desorption conditions was carried out. The values of the helium flow rate through the sorbent sample and the desorption time of the compounds are chosen to get the largest peak area. The regeneration of sorbent samples is carried out to provide the possibility of their reusage. Tenax-TA decomposes at lower temperatures compared to carbon sorbent and thus cannot be purified completely unlike the new monolith. The graphene-based sorbent is reusable and much cheaper in the manufacture than imported polymer Tenax-TA since it is made of domestic materials.

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