Transfer hydrogenation of carbon dioxide via bicarbonate promoted by bifunctional C–N chelating Cp*Ir complexes

2020 ◽  
Vol 56 (73) ◽  
pp. 10762-10765
Author(s):  
Yasuhiro Sato ◽  
Yoshihito Kayaki ◽  
Takao Ikariya
Keyword(s):  
Carbon Dioxide ◽  
Transfer Hydrogenation ◽  
Turnover Number ◽  
Mild Conditions ◽  
Carbonate Salts ◽  
Hydrogenation Of Carbon Dioxide

Metal–NH cooperative Ir complexes having a C–N chelate effectively promoted the reduction of bicarbonate and half-carbonate salts formed from CO2 in 2-propanol under mild conditions to produce formate salts with a maximum turnover number of 3200.

scholarly journals Correction: Transfer hydrogenation of carbon dioxide and bicarbonate from glycerol under aqueous conditions

2020 ◽  
Vol 56 (19) ◽  
pp. 2956-2956
Author(s):  
Jacob M. Heltzel ◽  
Matthew Finn ◽  
Diana Ainembabazi ◽  
Kai Wang ◽  
Adelina M. Voutchkova-Kostal
Keyword(s):  
Carbon Dioxide ◽  
Transfer Hydrogenation ◽  
Aqueous Conditions ◽  
Hydrogenation Of Carbon Dioxide

Correction for ‘Transfer hydrogenation of carbon dioxide and bicarbonate from glycerol under aqueous conditions’ by Jacob M. Heltzel et al., Chem. Commun., 2018, 54, 6184–6187.

A highly active copper catalyst for the hydrogenation of carbon dioxide to formate under ambient conditions

2020 ◽  
Vol 49 (9) ◽  
pp. 2994-3000
Author(s):  
Karan Chaudhary ◽  
Manoj Trivedi ◽  
D. T. Masram ◽  
Abhinav Kumar ◽  
Girijesh Kumar ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Copper Catalyst ◽  
Catalytic Conversion ◽  
Ambient Conditions ◽  
Turnover Number ◽  
Highly Active ◽  
Tin Metal ◽  
Hydrogenation Of Carbon Dioxide

Catalytic conversion of CO2via hydrogenation using in situ gaseous H2 (granulated tin metal and concentrated HCl) to produce the formate salt (HCO2−) with turnover number (TON) values of 326 to 1.065 × 105 in 12 h to 48 h of reaction at 25 °C to 80 °C has been reported.

Transfer Hydrogenation of Carbon Dioxide to Methanol Using a Molecular Ruthenium‐Phosphine Catalyst

ChemCatChem ◽  
2019 ◽  
Vol 11 (15) ◽  
pp. 3371-3375 ◽  
Author(s):  
Niklas Westhues ◽  
Jürgen Klankermayer
Keyword(s):  
Carbon Dioxide ◽  
Transfer Hydrogenation ◽  
Hydrogenation Of Carbon Dioxide

Transfer hydrogenation of carbon dioxide and bicarbonate from glycerol under aqueous conditions

2018 ◽  
Vol 54 (48) ◽  
pp. 6184-6187 ◽  
Author(s):  
Jacob M. Heltzel ◽  
Matthew Finn ◽  
Diana Ainembabazi ◽  
Kai Wang ◽  
Adelina M. Voutchkova-Kostal
Keyword(s):  
Carbon Dioxide ◽  
Lactic Acid ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Waste Streams ◽  
Catalytic Transfer ◽  
Aqueous Conditions ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

Catalytic transfer hydrogenation of CO2 from glycerol to afford formic and lactic acid is an attractive path to valorizing two waste streams. The process is significantly more thermodynamically favorable than direct CO2 hydrogenation.

scholarly journals Ruthenium Inserted Hydrotalcite (Ru-HT) Heterogeneous Catalyst for the Kinetic Studies of Selective Hydrogenation of Carbon Dioxide to Formic Acid

2021 ◽  
Author(s):  
Minaxi S. Maru ◽  
Sanwala Ram ◽  
Noorul Hasan Khan ◽  
Ram Sambhar Shukla
Keyword(s):  
Carbon Dioxide ◽  
Formic Acid ◽  
Heterogeneous Catalyst ◽  
Selective Hydrogenation ◽  
Kinetic Studies ◽  
Turnover Number ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

The kinetic studies have been done for the base-free hydrogenation of CO2 to formic acid using heterogeneous ruthenium inserted hydrotalcite (Ru-HT) catalyst. An impressive Turnover Number (TON = 11389) was...

Catalytic Hydrogenation of Carbon Dioxide to Fuels

2014 ◽  
Vol 18 (10) ◽  
pp. 1335-1345 ◽  
Author(s):  
Xuecheng Yan ◽  
Han Guo ◽  
Dongjiang Yang ◽  
Shilun Qiu ◽  
Xiangdong Yao
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Hydrogenation ◽  
Hydrogenation Of Carbon Dioxide

Ruthenium(II)-Catalyzed Hydrogenation of Carbon Dioxide to Formic Acid. Theoretical Study of Real Catalyst, Ligand Effects, and Solvation Effects

2005 ◽  
Vol 127 (11) ◽  
pp. 4021-4032 ◽  
Author(s):  
Yu-ya Ohnishi ◽  
Tadashi Matsunaga ◽  
Yoshihide Nakao ◽  
Hirofumi Sato ◽  
Shigeyoshi Sakaki
Keyword(s):  
Carbon Dioxide ◽  
Formic Acid ◽  
Theoretical Study ◽  
Solvation Effects ◽  
Ligand Effects ◽  
Hydrogenation Of Carbon Dioxide
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