Investigating the effect of a fluoroethylene carbonate additive on lithium deposition and the solid electrolyte interphase in lithium metal batteries using in situ NMR spectroscopy

An in situ NMR study of Li deposition and the SEI on Li metal. Isotope exchange measurements reveal the fast transport properties in the SEI formed with FEC and the accelerated SEI formation rate, in part explaining the homogeneous electrodeposition using FEC additives.

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Correction: Investigating the effect of a fluoroethylene carbonate additive on lithium deposition and the solid electrolyte interphase in lithium metal batteries using in situ NMR spectroscopy

Journal of Materials Chemistry A ◽

10.1039/d0ta90183k ◽

2020 ◽

Vol 8 (35) ◽

pp. 18388-18388

Author(s):

Anna B. Gunnarsdóttir ◽

Sundeep Vema ◽

Svetlana Menkin ◽

Lauren E. Marbella ◽

Clare P. Grey

Keyword(s):

Nmr Spectroscopy ◽

Solid Electrolyte ◽

Solid Electrolyte Interphase ◽

Lithium Metal ◽

Lithium Metal Batteries ◽

Lithium Deposition ◽

Fluoroethylene Carbonate ◽

Fluoroethylene Carbonate Additive ◽

In Situ Nmr Spectroscopy

Correction for ‘Investigating the effect of a fluoroethylene carbonate additive on lithium deposition and the solid electrolyte interphase in lithium metal batteries using in situ NMR spectroscopy’ by Anna B. Gunnarsdóttir et al., J. Mater. Chem. A, 2020, 8, 14975–14992, DOI: 10.1039/D0TA05652A

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Noninvasive In Situ NMR Study of “Dead Lithium” Formation and Lithium Corrosion in Full-Cell Lithium Metal Batteries

Journal of the American Chemical Society ◽

10.1021/jacs.0c10258 ◽

2020 ◽

Vol 142 (49) ◽

pp. 20814-20827

Author(s):

Anna B. Gunnarsdóttir ◽

Chibueze V. Amanchukwu ◽

Svetlana Menkin ◽

Clare P. Grey

Keyword(s):

Lithium Metal ◽

Full Cell ◽

Lithium Metal Batteries ◽

Nmr Study ◽

In Situ Nmr

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In Situ DRIFTS Analysis of Solid Electrolyte Interphase of Si-Based Anode with and without Fluoroethylene Carbonate Additive

Journal of The Electrochemical Society ◽

10.1149/2.0681714jes ◽

2017 ◽

Vol 164 (14) ◽

pp. A3641-A3648 ◽

Cited By ~ 10

Author(s):

Yonas Beyene Yohannes ◽

Shawn D. Lin ◽

Nae-Lih Wu

Keyword(s):

Solid Electrolyte ◽

Solid Electrolyte Interphase ◽

In Situ Drifts ◽

Fluoroethylene Carbonate ◽

Fluoroethylene Carbonate Additive

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The Importance of Interphases in Energy Storage Devices: Methods and Strategies to Investigate and Control Interfacial Processes

Physchem ◽

10.3390/physchem1010003 ◽

2021 ◽

Vol 1 (1) ◽

pp. 26-44

Author(s):

Chiara Ferrara ◽

Riccardo Ruffo ◽

Piercarlo Mustarelli

Keyword(s):

Energy Storage ◽

Solid Electrolyte Interphase ◽

Lithium Ion ◽

Lithium Metal ◽

Energy Storage Devices ◽

Storage Devices ◽

Lithium Metal Batteries ◽

And Control ◽

Near Future

Extended interphases are playing an increasingly important role in electrochemical energy storage devices and, in particular, in lithium-ion and lithium metal batteries. With this in mind we initially address the differences between the concepts of interface and interphase. After that, we discuss in detail the mechanisms of solid electrolyte interphase (SEI) formation in Li-ion batteries. Then, we analyze the methods for interphase characterization, with emphasis put on in-situ and operando approaches. Finally, we look at the near future by addressing the issues underlying the lithium metal/electrolyte interface, and the emerging role played by the cathode electrolyte interphase when high voltage materials are employed.

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Mesoscopic simulations of the in situ NMR spectra of porous carbon based supercapacitors: Electronic structure and adsorbent reorganisation effects

Physical Chemistry Chemical Physics ◽

10.1039/d1cp02130c ◽

2021 ◽

Author(s):

Anagha Sasikumar ◽

Anouar Belhboub ◽

Camille Bacon ◽

Alexander C. Forse ◽

John Griffin ◽

...

Keyword(s):

Electronic Structure ◽

Nmr Spectroscopy ◽

Molecular Species ◽

Porous Carbon ◽

Nmr Spectra ◽

Charge Storage ◽

In Situ Nmr Spectroscopy ◽

In Situ Nmr ◽

Carbon Based

In situ NMR spectroscopy is a powerful technique to investigate charge storage mechanisms in carbon-based supercapacitors thanks to its ability to distinguish ionic and molecular species adsorbed in the porous...

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Non-Selective Dimerization of Vinyl Silanes by the Putative (Phenanthroline)PdMe Cation to 1,4-Bis(trialkoxysilyl)butenes

Inorganics ◽

10.3390/inorganics6040102 ◽

2018 ◽

Vol 6 (4) ◽

pp. 102

Author(s):

Sandun Perera ◽

Michael Findlater

Keyword(s):

Nmr Spectroscopy ◽

Palladium Complex ◽

Organic Products ◽

Vinyl Silanes ◽

In Situ Nmr Spectroscopy ◽

In Situ Nmr ◽

Moderate Yield

Activation of the dialkylpalladium complex (phen)Pd(CH3)2 (phen = 1,10-phenanthroline) with B(C6F5)3 affords a competent catalyst for the dimerization of vinyl silanes. All organic products of the catalytic dimerization of trialkoxyvinylsilanes were characterized by in situ NMR spectroscopy and GC–MS. The putative palladium cation was characterized by NMR spectroscopy. Upon activation, the palladium complex generated products in moderate yield (60–70%) and selectivity (~60:40, dimer:disproportionation products).

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