Ratiometric electrochemical sensor for bisphenol A detection using glassy carbon electrode modified with poly(toluidine blue)/gold nanoparticle composite

2021 ◽  
Author(s):  
Zhiyuan Sun ◽  
Qin Xiao ◽  
Jingjing Tang ◽  
Qianfen Zhuang ◽  
Yong Wang

A ratiometric electrochemical sensor for bisphenol A (BPA) detection is established using glassy carbon electrode modified with poly(toluidine blue)/gold nanoparticle composite (PTB/AuNP/GCE). The ratiometric signal, namely, the oxidation peak current...


2015 ◽  
Vol 7 (19) ◽  
pp. 8094-8099 ◽  
Author(s):  
Jie Ren ◽  
Jinfen Gu ◽  
Li Tao ◽  
Mengqi Yao ◽  
Xiaoci Yang ◽  
...  

A well-packed film of AuNP/PIL was formed on the GCE surface.



2020 ◽  
Vol 11 (2) ◽  
pp. 9266-9277

A simple and rapid electrochemical sensor based on modified graphite nanoparticle with phosphotungstic acid and Nafion (GN–PTA–nafion) on glassy carbon electrode (GCE) has been developed for detecting bisphenol A (BPA). The GN was characterized using a scanning electron microscope (SEM) and X-ray diffractometer (XRD), while the modified GCE was characterized using differential pulse voltammetry (DPV) and cyclic voltammetry (CV). Several parameters such as GN concentration, scan rate, equilibrium time, and pH of phosphate buffer were optimized in this study. The GN–PTA–Nafion modified GCE that consists of graphite nanoparticle with a large surface area showed better and faster electron transfer, whereas the phosphotungstic acid (PTA) increased the sensitivity of the electrode for BPA detection. Good electrochemical performances for analyzing BPA, with a detection limit of 0.3995 mol L-1, as well as good reproducibility (RSD 2.51%) were obtained. The modified electrode showed that it had short analysis time, inexpensive and good sensitivity for BPA detection.



2016 ◽  
Vol 8 (16) ◽  
pp. 3333-3338 ◽  
Author(s):  
Jun Wan ◽  
Yuxiao Si ◽  
Chao Li ◽  
Kun Zhang

A facile and eco-friendly electrochemical sensor based on a multi-walled carbon nanotubes/polythiophene/Pt nanocomposites-modified glassy carbon electrode for determination of bisphenol A (BPA) was constructed using the MWCNT/PTh/Pt nanocomposites to modify glassy carbon (GC).







2020 ◽  
Vol 16 (4) ◽  
pp. 424-437
Author(s):  
Kubra Ozturk ◽  
Nurgul K. Bakirhan ◽  
Sibel A. Ozkan ◽  
Bengi Uslu

Background:: new and selective electrochemical sensor was developed for the determination of levocetirizine dihydrochloride, which is an antihistaminic drug. Method:: The investigation was performed by using cyclic, differential pulse and square wave voltammetric methods on the β-cyclodextrin modified glassy carbon electrode. It is thereby planned to obtain information about levocetirizine determination and its mechanism. Result:: The efficiency of experimental parameters including pH, scan rate, and accumulation potential and time on the anodic response of levocetirizine dihydrochloride was studied. By employing the developed method and under optimized conditions, the current showed linear dependence with a concentration in the range between 2 × 10-8 M and 6 × 10-6 M in pH 2.0 Britton Robinson (BR) buffer. Conclusion:: The achieved limits of detection and quantification were found as 3.73 × 10-10 M and 1.24 × 10-9 M, respectively. In addition, the possibility of applying the developed sensor for real sample analysis was investigated, so β-cyclodextrin modified glassy carbon electrode was used to determine levocetirizine dihydrochloride in Xyzal® tablet dosage form. Finally, this sensor was successfully applied to the real sample as a selective, simple, reproducible, repeatable electrochemical sensor.



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