Stabilizing Na metal anode with NaF interface on spent cathode carbon from aluminum electrolysis

2021 ◽  
Author(s):  
Yangyang Xie ◽  
Junxian Hu ◽  
Liuyun Zhang ◽  
Aonan Wang ◽  
Jingqiang Zheng ◽  
...  

We report the spent cathode carbon (SCC) with NaF interface from aluminum electrolysis as Na metal anode host. Benefit from the superior ion conductivity and high shear modulus. The natural...

2020 ◽  
Vol 17 ◽  
pp. 100465
Author(s):  
Tiancheng Liu ◽  
Zezhou Lin ◽  
Dong Wang ◽  
Man Zhang ◽  
Qiyang Hu ◽  
...  

2012 ◽  
pp. 1355-1357
Author(s):  
Gao Feng ◽  
Feng Naixiang ◽  
Niu Qingren ◽  
He Hua ◽  
Han Liguo ◽  
...  

2016 ◽  
Vol 113 (47) ◽  
pp. 13313-13317 ◽  
Author(s):  
Yutao Li ◽  
Weidong Zhou ◽  
Xi Chen ◽  
Xujie Lü ◽  
Zhiming Cui ◽  
...  

A solid electrolyte with a high Li-ion conductivity and a small interfacial resistance against a Li metal anode is a key component in all-solid-state Li metal batteries, but there is no ceramic oxide electrolyte available for this application except the thin-film Li-P oxynitride electrolyte; ceramic electrolytes are either easily reduced by Li metal or penetrated by Li dendrites in a short time. Here, we introduce a solid electrolyte LiZr2(PO4)3 with rhombohedral structure at room temperature that has a bulk Li-ion conductivity σLi = 2 × 10−4 S⋅cm−1 at 25 °C, a high electrochemical stability up to 5.5 V versus Li+/Li, and a small interfacial resistance for Li+ transfer. It reacts with a metallic lithium anode to form a Li+-conducting passivation layer (solid-electrolyte interphase) containing Li3P and Li8ZrO6 that is wet by the lithium anode and also wets the LiZr2(PO4)3 electrolyte. An all-solid-state Li/LiFePO4 cell with a polymer catholyte shows good cyclability and a long cycle life.


2018 ◽  
Vol 40 ◽  
pp. 21-29 ◽  
Author(s):  
Jin Xiao ◽  
Jie Yuan ◽  
Zhongliang Tian ◽  
Kai Yang ◽  
Zhen Yao ◽  
...  

Author(s):  
Prabhu Shankar ◽  
Jaehyung Ju ◽  
Joshua D. Summers ◽  
John C. Ziegert

This paper presents the analytical model to predict the effective in-plane shear modulus G12* for auxetic honeycomb mesostructure with sinusoidal re-entrant wall. Also, a comparative study is conducted on the ability of the sinusoidal mesostructure over auxetic mesostructure for high shear flexure. In an effort to design components with high shear flexure, the re-entrant wall of the auxetic honeycomb is replaced with a sinusoidal wall. Existing analytical models that predict the effective in-plane elastic properties for auxetic honeycomb mesostructure are limited to straight re-entrant wall. In order to predict the effective in plane shear modulus, G12*, for conceptual design study, an analytical model is needed. The principle of energy methods is used to determine the effective in-plane shear modulus and is verified with the solution in ABAQUS. The analytical model is in agreement with the computational model with a 10% maximum error over a wide range of cell wall thickness and shear strain. The two structures are designed to possess the same equivalent shear modulus and the degree of shear flexure is measured computationally in terms of yield shear strain. The sinusoidal structure introduces nonlinearity with increase in cell wall thickness and shear strain. This nonlinearity causes the sinusoidal auxetic mesostructure to have low shear flexure at a high shear modulus which is higher than about 10MPa. However, it is marginally better than auxetic mesostructure at a low shear modulus which is 10MPa and less.


2008 ◽  
Vol 20 (8) ◽  
pp. 085221 ◽  
Author(s):  
Sami Kamran ◽  
Kuiying Chen ◽  
Liang Chen ◽  
Linruo Zhao
Keyword(s):  

Sign in / Sign up

Export Citation Format

Share Document