An Organodiselenide Containing Electrolyte Enables Sulfurized Polyacrylonitrile Cathodes with Fast Redox Kinetics in Li-S batteries

2021 ◽  
Author(s):  
Wei Zhang ◽  
Qiang Wu ◽  
Ziqi Zeng ◽  
Chuang Yu ◽  
Shijie Cheng ◽  
...  
Keyword(s):  
Liquid Interface ◽  
Electrolyte Additive ◽  
Redox Kinetics ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Kinetics Of

A soluble organoselenide compound, phenyl diselenide (PDSe), is employed as a soluble electrolyte additive to enhance the kinetics of sulfurized polyacrylonitrile cathode, in which radical exchange in the solid-liquid interface...

Adsorption Kinetics of Polyvinyl Acetate Adsorbed at the Solid-Liquid Interface

1991 ◽  
Vol 248 ◽  
Author(s):  
H. Terashima ◽  
K. Kanehashi ◽  
N. Imai
Keyword(s):  
Slow Rate ◽  
Polyvinyl Acetate ◽  
Adsorption Equilibrium ◽  
Initial Rate ◽  
Unit Area ◽  
Liquid Interface ◽  
Kinetics Of Adsorption ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Kinetics Of

AbstractThe kinetics of adsorption of polyvinyl acetate at the solid-liquid interface has been studied to verify the correctness of a description in a paper [Peterson and Kwel, J.Phys.Chem. 65, 1330(1961)] : “the initial rate of adsorption of polyvinyl acetate was found to be rapid”. This is inconsistent with the widely accepted knowledge that polymer adsorption is a slow process. Polyvinyl acetate (Mw = 124,800) was adsorbed from benzene (0.001 to 0.05 mg ml−1) onto mica at 295.5 K. The adsorbed amount per unit area i.e. adsorbance has been determined as a function of incubation time using an ultramicrobalance [Mettler UM3]. The results obtained show that the adsorbance rises rapidly at the beginning of adsorption and then reaches an apparent plateau, where the adsorbance still increases at negligibly slow rate in comparison with the initial rate. The Peterson and Kwei's results have been confirmed to be correct. We regarded the plateau as an adsorption equilibrium and constructed adsorption isotherms, in which the Peterson and Kwei's results were incorporated. These isotherms are found to be less dependent on concentration in the dilute region concerned. This dependency is in agreement with the prediction of the Scheutjens and Fleer theory based on the loop-train-tail model.

Kinetics of exchange between adsorbed and free polymers at a solid/liquid interface

1989 ◽  
Vol 22 (6) ◽  
pp. 2677-2682 ◽  
Author(s):  
Emile Pefferkorn ◽  
Abdelkrim Haouam ◽  
Raphael Varoqui
Keyword(s):  
Liquid Interface ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Kinetics Of

Growth kinetics of intermediate compounds at a planar solid-solid or solid-liquid interface by diffusion mechanisms

1997 ◽  
Vol 82 (12) ◽  
pp. 6001-6007 ◽  
Author(s):  
André Coulet ◽  
Karine Bouche ◽  
Francis Marinelli ◽  
Francoise Barbier
Keyword(s):  
Growth Kinetics ◽  
Liquid Interface ◽  
Diffusion Mechanisms ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Kinetics Of
Sign in / Sign up

Export Citation Format

Share Document